A study of dimethylferrocene diffusion and electrode kinetics using microelectrode voltammetry in poly(ethylene glycol) solvent
文献类型：期刊论文
| 作者 | Zhou HF ; Gu NY ; Dong SJ |
| 刊名 | journal of solid state electrochemistry
 |
| 出版日期 | 1999 |
| 卷号 | 3期号:2页码:82-86 |
| 关键词 | SOLID-STATE VOLTAMMETRY TRANSFER RATE CONSTANTS MICRODISK ELECTRODES REDOX POLYMER VOLTAMMOGRAMS DYNAMICS |
| ISSN号 | 1432-8488 |
| 通讯作者 | dong, sj, chinese acad sci, changchun inst appl chem, electroanalyt chem lab, changchun 130022, peoples r china |
| 中文摘要 | the heterogeneous electron transfer rate constant (k(s)) of dimethylferrocene (dmfc) was estimated using cyclic voltammetric peak potential separations taken typically in a mixed diffusion geometry regime in a polyelectrolyte, and the diffusion coefficient (d) of dmfc was obtained using a steady-state voltammogram. the heterogeneous electron transfer rate constant and diffusion coefficient are both smaller by about 100-fold in the polymeric solvent than in the monomeric solvent. the results are in agreement with the difference of longitudinal dielectric relaxation time (tau(l)) in the two kinds of solvents, poly(ethylene glycol) (peg) and ch3cn, indicating that k(s) varies inversely with tau(l); k(s), is proportional to d of dmfc. both d and k(s) of dmfc in peg containing different supporting electrolytes and at different temperatures have been estimated. these results show that d and k(s) of dmfc increase with increasing temperature in the polyelectrolyte, whereas they vary only slightly with changing the supporting electrolyte. |
| 收录类别 | CSCD收录国内期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000078455800002 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/22043]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhou HF,Gu NY,Dong SJ. A study of dimethylferrocene diffusion and electrode kinetics using microelectrode voltammetry in poly(ethylene glycol) solvent[J]. journal of solid state electrochemistry,1999,3(2):82-86. |
| APA | Zhou HF,Gu NY,&Dong SJ.(1999).A study of dimethylferrocene diffusion and electrode kinetics using microelectrode voltammetry in poly(ethylene glycol) solvent.journal of solid state electrochemistry,3(2),82-86. |
| MLA | Zhou HF,et al."A study of dimethylferrocene diffusion and electrode kinetics using microelectrode voltammetry in poly(ethylene glycol) solvent".journal of solid state electrochemistry 3.2(1999):82-86. |
入库方式： OAI收割
来源：长春应用化学研究所
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