Synthesis, electrical properties and crystal structure of a new radical-ion salt based on pi-extended bis(TTF) and a Keggin heteropolymolybdate
文献类型：期刊论文
| 作者 | Peng J ; Wang E ; Zhou YS ; Xing Y ; Jia HQ ; Lin YH ; Shen YJ |
| 刊名 | journal of the chemical society-dalton transactions
 |
| 出版日期 | 1998 |
| 期号 | 22页码:3865-3869 |
| 关键词 | TETRATHIAFULVALENES SOLV=H2O COMPLEX |
| ISSN号 | 0300-9246 |
| 通讯作者 | wang e |
| 中文摘要 | by electrocrystallization of 2,6-[4,5-bis(n-butylsulfanyl)-1,3-dithiol-2-ylidene]-4,8-bis(6-iodo-n-hexyloxy)-1,3,5,7-tetrathia-s-indacene (bhbdti) and [nbu4](4)[simo12o40] in the mixed solvent chcl2ch2cl and ch3cn, the new radical-ion salt [c42h60cl2o2s12](2)[simo12o40] was prepared. it was characterized by means of ir and esr spectroscopy and x-ray diffraction. in the crystal structure, organic radical dications and silicomolybdate anions are alternatively arranged along the a axis to form a 1-d conducting layer. the organic layer consists of two isolated groups of bhbdti divided by the (011) plane without short interatomic contacts. however, in each group, bhbdti molecules associate with each other in a head to tail manner running along the [011] direction and face-to-face overlapping with a relative shift by approximately one ttf subunit along the long axis of the molecule and a slight shift along the short axis of the molecule with significantly short s ... s contacts. the room-temperature d.c. conductivity determined by the two-probe method is 10(-4) s cm(-1), suggesting that the compound is a semiconductor. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000077417500028 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/22635]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Peng J,Wang E,Zhou YS,et al. Synthesis, electrical properties and crystal structure of a new radical-ion salt based on pi-extended bis(TTF) and a Keggin heteropolymolybdate[J]. journal of the chemical society-dalton transactions,1998(22):3865-3869. |
| APA | Peng J.,Wang E.,Zhou YS.,Xing Y.,Jia HQ.,...&Shen YJ.(1998).Synthesis, electrical properties and crystal structure of a new radical-ion salt based on pi-extended bis(TTF) and a Keggin heteropolymolybdate.journal of the chemical society-dalton transactions(22),3865-3869. |
| MLA | Peng J,et al."Synthesis, electrical properties and crystal structure of a new radical-ion salt based on pi-extended bis(TTF) and a Keggin heteropolymolybdate".journal of the chemical society-dalton transactions .22(1998):3865-3869. |
入库方式： OAI收割
来源：长春应用化学研究所
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