The use of half-sandwich iridium dithiolate and diselenolate complexes, Cp*Ir(L)(ER)(2) (L = CO, PMe3, PPh3; ER = SPh, SePh, SeMe), for the synthesis of heterodimetallic compounds. The molecular structure of Cp*Ir(CO)(mu-SePh)(2)[Mo(CO)(4)]
文献类型：期刊论文
| 作者 | Herberhold M ; Jin GX ; Rheingold AL |
| 刊名 | journal of organometallic chemistry
 |
| 出版日期 | 1998 |
| 卷号 | 570期号:2页码:241-246 |
| 关键词 | PERFLUOROBENZENETHIOLATO COMPLEXES RHODIUM-PERFLUOROBENZENETHIOLATO CRYSTAL-STRUCTURES <(C5ME5)2RH2(MU-SC6F5)3><(C5ME5)RH(SC6F5)3> BEHAVIOR SELENIUM SULFUR |
| ISSN号 | 0022-328x |
| 通讯作者 | herberhold m |
| 中文摘要 | carbonyl-iridium half-sandwich compounds, cp*ir(co)(eph)(2) (e = s, se), were prepared by the photo-induced reaction of cp*ir(co)(2) with the diphenyl dichalcogenides, e2ph2, and used as neutral chelating ligands in carbonylmetal complexes such as cp*ir(co)(mu-eph)(2)[cr(co)(4)], cp*ir(co)(mu-eph)(2)[mo(co)(4)] and cp*ir(co)(mu-eph)(2)[fe(co)(3)], respectively. a trimethylphosphane - iridium analogue, cp*ir(pme3)(mu-seme)(2)[cr(co)(4)], was also obtained. the new heterodimetallic complexes were characterized by ir and nmr spectroscopy, and the molecular geometry of cp*ir(co)(mu-seph)(2)[mo(co)(4)] has been determined by a single crystal x-ray structure analysis. according to the long ir...mo distance (395.3(1) angstrom), direct metal-metal interactions appear to be absent. (c) 1998 elsevier science s.a. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000076724200010 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/22667]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Herberhold M,Jin GX,Rheingold AL. The use of half-sandwich iridium dithiolate and diselenolate complexes, Cp*Ir(L)(ER)(2) (L = CO, PMe3, PPh3; ER = SPh, SePh, SeMe), for the synthesis of heterodimetallic compounds. The molecular structure of Cp*Ir(CO)(mu-SePh)(2)[Mo(CO)(4)][J]. journal of organometallic chemistry,1998,570(2):241-246. |
| APA | Herberhold M,Jin GX,&Rheingold AL.(1998).The use of half-sandwich iridium dithiolate and diselenolate complexes, Cp*Ir(L)(ER)(2) (L = CO, PMe3, PPh3; ER = SPh, SePh, SeMe), for the synthesis of heterodimetallic compounds. The molecular structure of Cp*Ir(CO)(mu-SePh)(2)[Mo(CO)(4)].journal of organometallic chemistry,570(2),241-246. |
| MLA | Herberhold M,et al."The use of half-sandwich iridium dithiolate and diselenolate complexes, Cp*Ir(L)(ER)(2) (L = CO, PMe3, PPh3; ER = SPh, SePh, SeMe), for the synthesis of heterodimetallic compounds. The molecular structure of Cp*Ir(CO)(mu-SePh)(2)[Mo(CO)(4)]".journal of organometallic chemistry 570.2(1998):241-246. |
入库方式： OAI收割
来源：长春应用化学研究所
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