中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and polymerization of some macrocyclic (arylene ether sulfone) containing cardo groups and macrocyclic (arylene ether ketone sulfone) oligomers

文献类型:期刊论文

作者Jiang HY ; Chen TL ; Bo SQ ; Xu JP
刊名polymer
出版日期1998
卷号39期号:24页码:6079-6083
关键词RING-OPENING POLYMERIZATION BISPHENOL-A 1 PRECURSORS DIMER 2-DIBENZOYLBENZENE MOIETY
ISSN号0032-3861
通讯作者jiang hy
中文摘要some novel macrocyclic (arylene ether sulfone) containing cardo groups and (arylene ether ketone sulfone) oligomers have been synthesized in high yields by a nucleophilic aromatic substitution reaction of 4,4'-difluorophenylsulfone with bisphenols in the presence of anhydrous potassium carbonate under a pseudo-high-dilution condition. detailed structural characterization of these oligomers by matrix-assisted laser desorption/ionization-time of flight-mass spectrometry (maldi-tof-ms), fast atom bombardment mass spectrometry (f.a.b.-m.s.), nuclear magnetic resonance spectrometry (n.m.r.) and single-crystal x-ray structure analysis confirms their cyclic nature, and the composition of the oligomeric mixtures is provided by g.p.c. analysis. ring polymerization of cyclic oligomers 3a to a high molecular weight polymer with m-w of 59.1 k was achieved by heating at 290 degrees c for 40 min in the presence of a nucleophilic initiator. (c) 1998 elsevier science ltd. all rights reserved.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000075627300025
公开日期2010-11-04
源URL[http://202.98.16.49/handle/322003/22715]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Jiang HY,Chen TL,Bo SQ,et al. Synthesis and polymerization of some macrocyclic (arylene ether sulfone) containing cardo groups and macrocyclic (arylene ether ketone sulfone) oligomers[J]. polymer,1998,39(24):6079-6083.
APA Jiang HY,Chen TL,Bo SQ,&Xu JP.(1998).Synthesis and polymerization of some macrocyclic (arylene ether sulfone) containing cardo groups and macrocyclic (arylene ether ketone sulfone) oligomers.polymer,39(24),6079-6083.
MLA Jiang HY,et al."Synthesis and polymerization of some macrocyclic (arylene ether sulfone) containing cardo groups and macrocyclic (arylene ether ketone sulfone) oligomers".polymer 39.24(1998):6079-6083.

入库方式: OAI收割

来源:长春应用化学研究所

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