The rheological and extrusion behaviour of blends based on phenolphthalein poly(ether-ether-sulfone) and thermotropic liquid crystalline polymer
文献类型:期刊论文
作者 | Di YW ; D'Amore A ; Nicolais L ; Acierno D ; Nobile R ; Li BY |
刊名 | chemical research in chinese universities
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出版日期 | 1998 |
卷号 | 14期号:3页码:315-323 |
关键词 | WALL SLIP MORPHOLOGY POLYETHYLENE COPOLYESTER POLYSTYRENE COMPOSITES MELTS FLOW |
ISSN号 | 1005-9040 |
中文摘要 | a novel engineering thermoplastic, phenolphthalein poly (ether-ether-sulfone) (pes-c) was blended with a commercial thermotropic liquid crystalline polymer(tlcp), vectra a950, up to 30 weight percent of tlcp. a rheometrics dynamic spectrometer (rds-i) and a ceast capillary rheometer, a rheoscope 1000 were employed to investigate the melt rheology and extrusion behaviour at both the low and high shearing rates. the morphologies of the blends under different shearing were observed with a scanning electron microscope(sem) and correlated to the observed rheology. the principal normal stress differences measured with cone-and-plate geometry give a temperature-independent correlation for both blend and pes-c when they are plotted against shear stress. but the extrudate swell of the blends showed a strong temperature dependence at each shear stress. the concentration dependence of extrudate swell shows a contrary behaviour to that of the inorganic filled system. a reasonable hypothesis based on the relaxation and disorientation of tlcp during flowing in the capillary and exiting was given to explain it. the melt fracture was checked after extrusion from capillary and was discussed. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000075803900020 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/22733] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Di YW,D'Amore A,Nicolais L,et al. The rheological and extrusion behaviour of blends based on phenolphthalein poly(ether-ether-sulfone) and thermotropic liquid crystalline polymer[J]. chemical research in chinese universities,1998,14(3):315-323. |
APA | Di YW,D'Amore A,Nicolais L,Acierno D,Nobile R,&Li BY.(1998).The rheological and extrusion behaviour of blends based on phenolphthalein poly(ether-ether-sulfone) and thermotropic liquid crystalline polymer.chemical research in chinese universities,14(3),315-323. |
MLA | Di YW,et al."The rheological and extrusion behaviour of blends based on phenolphthalein poly(ether-ether-sulfone) and thermotropic liquid crystalline polymer".chemical research in chinese universities 14.3(1998):315-323. |
入库方式: OAI收割
来源:长春应用化学研究所
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