Polymerization of aniline in an aqueous system containing organic solvents
文献类型:期刊论文
作者 | Geng YH ; Li J ; Sun ZC ; Jing XB ; Wang FS |
刊名 | synthetic metals
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出版日期 | 1998 |
卷号 | 96期号:1页码:1-6 |
关键词 | CHEMICAL POLYMERIZATION PERNIGRANILINE BASE POLYANILINE OXIDATION EMERALDINE |
ISSN号 | 0379-6779 |
通讯作者 | jing xb |
中文摘要 | polyaniline (pan) with different molecular weight was prepared by adding organic solvents such as acetone, ethanol or thf into the polymerization mixture. open-circuit potential measurements showed that the polymerization rate was lowered by the addition of the organic solvent spectral studies showed that pan intermediate before the oxidant was consumed was pernigraniline and it was reduced to emeraldine base rapidly by aniline in the termination period. a mechanism of chain propagation was proposed. chain propagation and autoacceleration period were almost independent of addition of pernigraniline, and the autoacceleration of aniline polymerization is due to more rapid initiation rate. (c) 1998 published by elsevier science s.a. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000075637100001 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/22741] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Geng YH,Li J,Sun ZC,et al. Polymerization of aniline in an aqueous system containing organic solvents[J]. synthetic metals,1998,96(1):1-6. |
APA | Geng YH,Li J,Sun ZC,Jing XB,&Wang FS.(1998).Polymerization of aniline in an aqueous system containing organic solvents.synthetic metals,96(1),1-6. |
MLA | Geng YH,et al."Polymerization of aniline in an aqueous system containing organic solvents".synthetic metals 96.1(1998):1-6. |
入库方式: OAI收割
来源:长春应用化学研究所
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