Microelectrode voltammetric measurement of heterogeneous electron transfer rate constants for reduction of 7,7,8 ',8 '-tetracyanoquinodimethane in polymer electrolytes
文献类型：期刊论文
| 作者 | Zhou HF ; Ding LM ; Gu NY ; Dong SJ |
| 刊名 | electrochimica acta
 |
| 出版日期 | 1998 |
| 卷号 | 43期号:21-22页码:3353-3358 |
| 关键词 | SOLID-STATE VOLTAMMETRY POLY(ETHYLENE OXIDE) MICRODISK ELECTRODES FERROCENE DIFFUSION SOLVENT DYNAMICS INTERFACE CHRONOAMPEROMETRY VOLTAMMOGRAMS KINETICS MELTS |
| ISSN号 | 0013-4686 |
| 通讯作者 | dong sj |
| 中文摘要 | this paper presents a microelectrode voltammetric determination of heterogeneous electron transfer rate constants (k(s)) and diffusion coefficients (d) of 7,7,8',8 '-tetracyanoquinodimethane (tcnq) in polyelectrolytes. the diffusion coefficients are estimated using cyclic voltammetry under linear diffusion conditions, and the heterogeneous electron transfer rate constants are obtained under mixed linear and radial diffusion in the polyelectrolyte. k(s) and d increase with increasing temperature, and the activation barriers of the electrode reaction for reduction of tcnq are obtained. on the other hand, the dependencies of d and k(s) of tcnq on the size and charge of the counterion are compared in the polyelectrolyte. (c) 1998 elsevier science ltd. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000075658700029 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/22755]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhou HF,Ding LM,Gu NY,et al. Microelectrode voltammetric measurement of heterogeneous electron transfer rate constants for reduction of 7,7,8 ',8 '-tetracyanoquinodimethane in polymer electrolytes[J]. electrochimica acta,1998,43(21-22):3353-3358. |
| APA | Zhou HF,Ding LM,Gu NY,&Dong SJ.(1998).Microelectrode voltammetric measurement of heterogeneous electron transfer rate constants for reduction of 7,7,8 ',8 '-tetracyanoquinodimethane in polymer electrolytes.electrochimica acta,43(21-22),3353-3358. |
| MLA | Zhou HF,et al."Microelectrode voltammetric measurement of heterogeneous electron transfer rate constants for reduction of 7,7,8 ',8 '-tetracyanoquinodimethane in polymer electrolytes".electrochimica acta 43.21-22(1998):3353-3358. |
入库方式： OAI收割
来源：长春应用化学研究所
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