Synthesis and structural characterization of a novel polymeric praseodymium(III) complex with a new flexible double betaine
文献类型：期刊论文
| 作者 | Mao JG ; Wu HT ; Ni JZ ; Zhang HJ ; Mak TCW |
| 刊名 | journal of chemical crystallography
 |
| 出版日期 | 1998 |
| 卷号 | 28期号:3页码:177-183 |
| 关键词 | CRYSTAL-STRUCTURES LIGANDS SM |
| ISSN号 | 1074-1542 |
| 通讯作者 | mak tcw |
| 中文摘要 | a novel polymeric pr(iii) complex with a new double betaine, namely [{pr(l-1)(1.5)(h2o)(2)}(n)] [cloli4]3(n). nh(2)o (1) (l-1= 1,4-diazoniobicyclo[2,2,2]octane- 1,4-dipropionate), has been synthesized and characterized by x-ray analysis. in the title complex, the pr(iii) atom is nine-coordinated by seven oxygen atoms from five l-1 ligands and two aqua ligands. each pair of adjacent praseodymium(iii) atoms is linked by a pair of mu(3) chelating and bridging carboxylate groups, thus forming an infinite metal metal chain running parallel to the a direction, and such chains are cross-linked by flexible backbones of l-1 ligands into a three-dimensional network with the perchlorate anions and lattice water molecules accommodated in the interstitial space. the title complex crystallizes in the monoclinic space group p2(1)/n with a = 8.085(2), b = 14.316(3), c = 29.775(6) angstrom, beta = 103.04(3)degrees and z = 4. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000074595700003 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/22877]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Mao JG,Wu HT,Ni JZ,et al. Synthesis and structural characterization of a novel polymeric praseodymium(III) complex with a new flexible double betaine[J]. journal of chemical crystallography,1998,28(3):177-183. |
| APA | Mao JG,Wu HT,Ni JZ,Zhang HJ,&Mak TCW.(1998).Synthesis and structural characterization of a novel polymeric praseodymium(III) complex with a new flexible double betaine.journal of chemical crystallography,28(3),177-183. |
| MLA | Mao JG,et al."Synthesis and structural characterization of a novel polymeric praseodymium(III) complex with a new flexible double betaine".journal of chemical crystallography 28.3(1998):177-183. |
入库方式： OAI收割
来源：长春应用化学研究所
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