Gas-phase ion-molecule reactions of neutral C-60 with alkyl methyl ethers under chemical ionization conditions
文献类型:期刊论文
作者 | Ma L ; Liu ZY ; Xu YP ; Wang WJ ; Guo XH ; Liu SY |
刊名 | rapid communications in mass spectrometry
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出版日期 | 1998 |
卷号 | 12期号:12页码:790-792 |
关键词 | BUCKMINSTERFULLERENE C-60 MASS-SPECTROMETER CATIONS CYCLOADDITION FULLERENES CHEMISTRY ISOMERS C60 |
ISSN号 | 0951-4198 |
通讯作者 | liu sy |
中文摘要 | gas-phase ion-molecule reactions of buckminsterfullerene (c-60) with the ion systems generated from the self-chemical ionization of alkyl methyl ethers (ch3or, r = n-c2h5, n-c3h7, n-c4h9) were studied in the ion source of a mass spectrometer. the adduct cation [c60c2h5o](+) and protonated molecule [c60h](+) were observed as the major products. the former adduct ion was produced by the reactions of c-60 with the methoxymethyl ion [ch3och2](+), and the latter resulted from the proton transfer reactions from protonated alkyl methyl ethers to c-60 it is suggested that the [3+2] cycloadduct to a 6-6 bond of c-60 (a c-c bond common to two annulated six-membered rings) is the most favorable structure among the probable isomers of [c60c2h5o](+). (c) 1998 john wiley & sons, ltd. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000074279100008 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/22889] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Ma L,Liu ZY,Xu YP,et al. Gas-phase ion-molecule reactions of neutral C-60 with alkyl methyl ethers under chemical ionization conditions[J]. rapid communications in mass spectrometry,1998,12(12):790-792. |
APA | Ma L,Liu ZY,Xu YP,Wang WJ,Guo XH,&Liu SY.(1998).Gas-phase ion-molecule reactions of neutral C-60 with alkyl methyl ethers under chemical ionization conditions.rapid communications in mass spectrometry,12(12),790-792. |
MLA | Ma L,et al."Gas-phase ion-molecule reactions of neutral C-60 with alkyl methyl ethers under chemical ionization conditions".rapid communications in mass spectrometry 12.12(1998):790-792. |
入库方式: OAI收割
来源:长春应用化学研究所
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