Catalysis of hydrotalcite-like compounds in liquid phase oxidation: (I) phenol hydroxylation
文献类型:期刊论文
作者 | Zhu KZ ; Liu CB ; Ye XK ; Wu Y |
刊名 | applied catalysis a-general |
出版日期 | 1998 |
卷号 | 168期号:2页码:365-372 |
ISSN号 | 0926-860x |
关键词 | PILLARED HYDROTALCITE HYDROGEN-PEROXIDE MECHANISM |
通讯作者 | wu y |
中文摘要 | hydrotalcite-like compounds (htlcs): (cumalco3)-al-ii-htlcs, where m-ii=co2+, ni2+, cu2+, zn2+ and fe2+, were synthesized by coprecipitation and characterized with xrd and ir. the catalysis of these htlcs was studied in the phenol hydroxylation by h2o2 in liquid phase; then the effects of the ratio of cu/al, reaction temperature, solvent and ph of medium were investigated. it has been found that the uncalcined htlcs have higher activities than those of calcined samples in this reaction. the catalyst cualco3-htlcs having cu/al=3 efficiently oxidized phenol and gave high yields of the corresponding diphenols in appropriate reaction conditions. a tentative reaction mechanism is also proposed. (c) 1998 elsevier science b.v. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000073133500016 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/22991] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhu KZ,Liu CB,Ye XK,et al. Catalysis of hydrotalcite-like compounds in liquid phase oxidation: (I) phenol hydroxylation[J]. applied catalysis a-general,1998,168(2):365-372. |
APA | Zhu KZ,Liu CB,Ye XK,&Wu Y.(1998).Catalysis of hydrotalcite-like compounds in liquid phase oxidation: (I) phenol hydroxylation.applied catalysis a-general,168(2),365-372. |
MLA | Zhu KZ,et al."Catalysis of hydrotalcite-like compounds in liquid phase oxidation: (I) phenol hydroxylation".applied catalysis a-general 168.2(1998):365-372. |
入库方式: OAI收割
来源:长春应用化学研究所
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