A study on the diffusion of quinhydrone in polymer electrolyte
文献类型:期刊论文
作者 | Dong SJ ; Gu NY ; Zhou HF |
刊名 | journal of electroanalytical chemistry
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出版日期 | 1998 |
卷号 | 441期号:1-2页码:95-101 |
关键词 | FERROCENE DIFFUSION VOLTAMMETRY DEPENDENCE TRANSPORT |
ISSN号 | 0022-0728 |
通讯作者 | dong sj |
中文摘要 | the diffusion coefficients (d) of quinhydrone were estimated in polymer electrolytes by using non-steady-state chronoamperometry and steady-state current voltammetry. the d values have been estimated in polyethylene glycol (peg) containing different concentrations, and cations of supporting electrolytes, and in different solvents over a range of temperatures. the dependencies of electroactive probe diffusion coefficients on temperature, supporting electrolyte concentration and polymer chain length are discussed. the results show that d increases with increasing temperature and decreasing concentration of supporting electrolyte. the diffusion coefficient depends strongly on the length of polymer chain and decreases sharply with increasing polymer chain length. the contribution of electron self-exchange has been explored and it seems to be negligible here. (c) 1998 elsevier science s.a. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000072658500015 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/23007] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Dong SJ,Gu NY,Zhou HF. A study on the diffusion of quinhydrone in polymer electrolyte[J]. journal of electroanalytical chemistry,1998,441(1-2):95-101. |
APA | Dong SJ,Gu NY,&Zhou HF.(1998).A study on the diffusion of quinhydrone in polymer electrolyte.journal of electroanalytical chemistry,441(1-2),95-101. |
MLA | Dong SJ,et al."A study on the diffusion of quinhydrone in polymer electrolyte".journal of electroanalytical chemistry 441.1-2(1998):95-101. |
入库方式: OAI收割
来源:长春应用化学研究所
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