The electrochemistry of cytochrome c at a viologen-thiol self-assembled monolayer
文献类型:期刊论文
作者 | Li JH ; Cheng GJ ; Dong SJ |
刊名 | chemical research in chinese universities
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出版日期 | 1998 |
卷号 | 14期号:1页码:17-24 |
关键词 | GOLD ELECTRODE BEHAVIOR HEPTYLVIOLOGEN SYSTEMS SALTS |
ISSN号 | 1005-9040 |
中文摘要 | at the self-assembled monolayer (sam) of a thiol-functionalized viologen modified gold electrode, cytochrome c (cyt c) exhibits a quasi-reversible electrochemical reaction. the heterogeneous electron transfer rate constant of cyt c in 0.1 mol/l phosphate buffer solution(ph 6.96) is 0.164 cm.s(-1) at 500 mv/s. the adsorbed cyt c on the viologen sam forms a closely packed monolayer, whose average electron transfer rate is 4.85 s(-1) in the scan range of 50 to 500 mv/s. these results suggest that the sam of viologen-thiol is a relatively stable, ordered and well-behaved monolayer from an electrochemical standpoint and it promotes the electron transfer process of biomolecules on electrode surface well. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000072402400004 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/23027] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Li JH,Cheng GJ,Dong SJ. The electrochemistry of cytochrome c at a viologen-thiol self-assembled monolayer[J]. chemical research in chinese universities,1998,14(1):17-24. |
APA | Li JH,Cheng GJ,&Dong SJ.(1998).The electrochemistry of cytochrome c at a viologen-thiol self-assembled monolayer.chemical research in chinese universities,14(1),17-24. |
MLA | Li JH,et al."The electrochemistry of cytochrome c at a viologen-thiol self-assembled monolayer".chemical research in chinese universities 14.1(1998):17-24. |
入库方式: OAI收割
来源:长春应用化学研究所
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