The oxidative demethylation of 24-membered hexa-aza macrocyclic bicopper(I) complex - The mimicking for monooxygenase
文献类型：期刊论文
| 作者 | Hu MF ; Meng QG ; Shen CY ; Zhang JJ ; Meng N ; Luo QH |
| 刊名 | acta chimica sinica
 |
| 出版日期 | 1998 |
| 卷号 | 56期号:2页码:147-153 |
| 关键词 | BINUCLEAR COPPER(I) HYDROXYLATION COMPOUND CRYSTAL LIGAND SITES |
| ISSN号 | 0567-7351 |
| 通讯作者 | hu mf |
| 中文摘要 | by [2 + 2] schiff base condensation of 5 - bromo - 2 - methoxylbenzene - 1,3 - dicarboxaldehyde with diethylenetriamine, a new hexaaza 24 - membered macrocyclic ligand was obtained,which formed a macrocyclic binuclear copper(i) complex in the presence of [cu . (ch3cn)(4)]clo4. when the copper(i) complex was oxidized in air or oxygen, a new macrocyclic binuclear copper( ii) complex was obtained. the copper( ii.) complex was characterized by several methods and its oxidized products was characterized by h-1 nmr. the results show that during oxidation, a methoxyl group in the ligand ring broke; and the phenoxy - and water - bridged cu(ii) complex formed. in oxidation of monooxygenase such as ligninase, oxidative demethylation also happened. therefore this work mimicked this process for the first time by using macrocyclic complex. the quantity of absorbed oxygen and the absorption rate of oxygen were determined. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 中文 |
| WOS记录号 | WOS:000072419900008 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/23045]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Hu MF,Meng QG,Shen CY,et al. The oxidative demethylation of 24-membered hexa-aza macrocyclic bicopper(I) complex - The mimicking for monooxygenase[J]. acta chimica sinica,1998,56(2):147-153. |
| APA | Hu MF,Meng QG,Shen CY,Zhang JJ,Meng N,&Luo QH.(1998).The oxidative demethylation of 24-membered hexa-aza macrocyclic bicopper(I) complex - The mimicking for monooxygenase.acta chimica sinica,56(2),147-153. |
| MLA | Hu MF,et al."The oxidative demethylation of 24-membered hexa-aza macrocyclic bicopper(I) complex - The mimicking for monooxygenase".acta chimica sinica 56.2(1998):147-153. |
入库方式： OAI收割
来源：长春应用化学研究所
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