Synthesis and X-ray crystal structure of [(eta(5)-C5H5)Sm(mu-OC20H20N2O)](2)(mu-THF)(THF)(2): Mono(cyclopentadienyl)lanthanide complex bearing a C-2-symmetric tetradentate Schiff-base ligand
文献类型：期刊论文
| 作者 | Liu QC ; Ding MX ; Lin YH ; Xing Y |
| 刊名 | polyhedron
 |
| 出版日期 | 1998 |
| 卷号 | 17期号:4页码:555-559 |
| 关键词 | ENANTIOSELECTIVE EPOXIDATION CATALYSTS CHIRAL ORGANOLANTHANIDES ASYMMETRIC CATALYSIS POLYMERIZATION HYDROGENATION |
| ISSN号 | 0277-5387 |
| 通讯作者 | ding mx |
| 中文摘要 | cp2smcl(thf) reacts with 0.5 equivalent disodium salts of trans-(+/-)-n,n'-bis(salicylidene)-1,2-cyclohexanediamine give the title complex [(eta(5)-c5h5)sm(mu-oc20h20n2o)](2)(mu-thf)(thf)(2) (1). x-ray crystal determination shows that the molecule is a dimer, in which two (eta(5)c(5)h(5))sm(mu-oc20h20n2o) units are connected via a thf oxygen and two bridging oxygen atoms of schiff base ligands. the average sm-c distance is 2.78(7) angstrom, while those of sm-o (bridging thf oxygen) and schiff base oxygens are 2.79(3) and 2.43(4) angstrom; respectively. (c) 1998 elsevier science ltd. all rights reserved. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000072113100023 |
| 公开日期 | 2010-11-04 |
| 源URL | [http://202.98.16.49/handle/322003/23059]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu QC,Ding MX,Lin YH,et al. Synthesis and X-ray crystal structure of [(eta(5)-C5H5)Sm(mu-OC20H20N2O)](2)(mu-THF)(THF)(2): Mono(cyclopentadienyl)lanthanide complex bearing a C-2-symmetric tetradentate Schiff-base ligand[J]. polyhedron,1998,17(4):555-559. |
| APA | Liu QC,Ding MX,Lin YH,&Xing Y.(1998).Synthesis and X-ray crystal structure of [(eta(5)-C5H5)Sm(mu-OC20H20N2O)](2)(mu-THF)(THF)(2): Mono(cyclopentadienyl)lanthanide complex bearing a C-2-symmetric tetradentate Schiff-base ligand.polyhedron,17(4),555-559. |
| MLA | Liu QC,et al."Synthesis and X-ray crystal structure of [(eta(5)-C5H5)Sm(mu-OC20H20N2O)](2)(mu-THF)(THF)(2): Mono(cyclopentadienyl)lanthanide complex bearing a C-2-symmetric tetradentate Schiff-base ligand".polyhedron 17.4(1998):555-559. |
入库方式： OAI收割
来源：长春应用化学研究所
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