中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Electrochemical studies of a lanthanide heteropoly tungstate/molybdate complex in polypyrrole film electrode and its electrocatalytic reduction of bromate

文献类型:期刊论文

作者Dong SJ ; Cheng L ; Zhang XM
刊名electrochimica acta
出版日期1998
卷号43期号:5-6页码:563-568
关键词KEGGIN-TYPE HETEROPOLYANIONS HYDROGEN EVOLUTION REACTION SURFACE MODIFICATIONS POLYANILINE FILMS ANION BEHAVIOR ACTIVATION CATALYSTS POLYMERS REDOX
ISSN号0013-4686
通讯作者dong sj
中文摘要an electrode modified with a polybasic lanthanide heteropoly tungstate/molybdate complex k10h3[nd(simo7w4o39)(2)] entrapped into polypyrrole (ppy) film, denoted as nd(simo7w4)(2)-ppy, exhibits three couples of two-electron redox waves in ph 1-5 buffer solutions. the redox waves are surface-controlled at lower scan rates and diffusion-controlled at higher scan rates. the effects of ph on the electrochemical behavior of nd(simo7w4)(2) in ppy film were investigated in detail and compared with that of nd(simo7w4)(2) in aqueous solution. the various charge states of ppy during its redox process have peculiar effects on the relationship between ph and formal potentials of nd(simo7w4)(2)-ppy at different acidities. the nd(simo7w4)(2)-ppy cme can remarkably catalyze the electrochemical reduction of bromate with good stability. (c) 1997 elsevier science ltd.
收录类别SCI收录期刊论文
语种英语
WOS记录号WOS:000071023600014
公开日期2010-11-04
源URL[http://202.98.16.49/handle/322003/23107]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Dong SJ,Cheng L,Zhang XM. Electrochemical studies of a lanthanide heteropoly tungstate/molybdate complex in polypyrrole film electrode and its electrocatalytic reduction of bromate[J]. electrochimica acta,1998,43(5-6):563-568.
APA Dong SJ,Cheng L,&Zhang XM.(1998).Electrochemical studies of a lanthanide heteropoly tungstate/molybdate complex in polypyrrole film electrode and its electrocatalytic reduction of bromate.electrochimica acta,43(5-6),563-568.
MLA Dong SJ,et al."Electrochemical studies of a lanthanide heteropoly tungstate/molybdate complex in polypyrrole film electrode and its electrocatalytic reduction of bromate".electrochimica acta 43.5-6(1998):563-568.

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来源:长春应用化学研究所

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