Electrochemical studies of a lanthanide heteropoly tungstate/molybdate complex in polypyrrole film electrode and its electrocatalytic reduction of bromate
文献类型:期刊论文
作者 | Dong SJ ; Cheng L ; Zhang XM |
刊名 | electrochimica acta
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出版日期 | 1998 |
卷号 | 43期号:5-6页码:563-568 |
关键词 | KEGGIN-TYPE HETEROPOLYANIONS HYDROGEN EVOLUTION REACTION SURFACE MODIFICATIONS POLYANILINE FILMS ANION BEHAVIOR ACTIVATION CATALYSTS POLYMERS REDOX |
ISSN号 | 0013-4686 |
通讯作者 | dong sj |
中文摘要 | an electrode modified with a polybasic lanthanide heteropoly tungstate/molybdate complex k10h3[nd(simo7w4o39)(2)] entrapped into polypyrrole (ppy) film, denoted as nd(simo7w4)(2)-ppy, exhibits three couples of two-electron redox waves in ph 1-5 buffer solutions. the redox waves are surface-controlled at lower scan rates and diffusion-controlled at higher scan rates. the effects of ph on the electrochemical behavior of nd(simo7w4)(2) in ppy film were investigated in detail and compared with that of nd(simo7w4)(2) in aqueous solution. the various charge states of ppy during its redox process have peculiar effects on the relationship between ph and formal potentials of nd(simo7w4)(2)-ppy at different acidities. the nd(simo7w4)(2)-ppy cme can remarkably catalyze the electrochemical reduction of bromate with good stability. (c) 1997 elsevier science ltd. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000071023600014 |
公开日期 | 2010-11-04 |
源URL | [http://202.98.16.49/handle/322003/23107] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Dong SJ,Cheng L,Zhang XM. Electrochemical studies of a lanthanide heteropoly tungstate/molybdate complex in polypyrrole film electrode and its electrocatalytic reduction of bromate[J]. electrochimica acta,1998,43(5-6):563-568. |
APA | Dong SJ,Cheng L,&Zhang XM.(1998).Electrochemical studies of a lanthanide heteropoly tungstate/molybdate complex in polypyrrole film electrode and its electrocatalytic reduction of bromate.electrochimica acta,43(5-6),563-568. |
MLA | Dong SJ,et al."Electrochemical studies of a lanthanide heteropoly tungstate/molybdate complex in polypyrrole film electrode and its electrocatalytic reduction of bromate".electrochimica acta 43.5-6(1998):563-568. |
入库方式: OAI收割
来源:长春应用化学研究所
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