Formation of self-assembled monolayers on gold electrodes with inclusion complexes of cyclodextrins and viologens
文献类型：期刊论文
| 作者 | Yan JC ; Dong SJ ; Li JH ; Chen WQ |
| 刊名 | journal of the electrochemical society
 |
| 出版日期 | 1997 |
| 卷号 | 144期号:11页码:3858-3865 |
| 关键词 | ALPHA-CYCLODEXTRIN BETA-CYCLODEXTRIN ELECTROCHEMICAL-BEHAVIOR DISTANCE DEPENDENCE TRANSFER KINETICS REDOX CENTERS SPECTROSCOPY SOLVENT PATHWAY MODEL |
| ISSN号 | 0013-4651 |
| 通讯作者 | yan jc |
| 中文摘要 | a novel kind of electroactive self-assembled monolayer (sam) has been successfully prepared through the following procedure: (1) formation of inclusion complexes (denoted as cd/c8vc10sh) between n-(n-octyl)-n'-(10-mercaptodecyl)-4,4'-bipyridinium dibromide (c8vc10sh) and alpha-, beta-cyclodextrin (cd) under a mild condition; (2) spontaneous formation of sam of cd/c8vc10sh on gold electrodes at room temperature. high-resolution h-1-nmr spectrum was used to confirm the formation of cd/c8vc10sh. cyclic voltammetry was used to characterize the redox behavior of the resulting monolayers and chronoamperometry and electrochemical impedance spectroscopy to characterize their electron transfer kinetics. it was found that the redox sites in sam of cd/c8vc10sh are effectively diluted, with a larger electron transfer rate constant than that of sam of c8vc10sh. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/23955]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Yan JC,Dong SJ,Li JH,et al. Formation of self-assembled monolayers on gold electrodes with inclusion complexes of cyclodextrins and viologens[J]. journal of the electrochemical society,1997,144(11):3858-3865. |
| APA | Yan JC,Dong SJ,Li JH,&Chen WQ.(1997).Formation of self-assembled monolayers on gold electrodes with inclusion complexes of cyclodextrins and viologens.journal of the electrochemical society,144(11),3858-3865. |
| MLA | Yan JC,et al."Formation of self-assembled monolayers on gold electrodes with inclusion complexes of cyclodextrins and viologens".journal of the electrochemical society 144.11(1997):3858-3865. |
入库方式： OAI收割
来源：长春应用化学研究所
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