Comparison of non-linear optical susceptibilities of KNbO3 and LiNbO3
文献类型:期刊论文
作者 | Xue DF ; Zhang SY |
刊名 | journal of physics and chemistry of solids
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出版日期 | 1997 |
卷号 | 58期号:9页码:1399-1402 |
关键词 | REFRACTIVE-INDEXES ORTHORHOMBIC KNBO3 CRYSTAL PHASE BOND |
ISSN号 | 0022-3697 |
中文摘要 | from the chemical bond viewpoint, second-order non-linear optical (nlo) tenser coefficients of knbo3 and linbo3 crystals have been calculated. by using the bond-valence theory of complex crystals and the modified bond-charge model, we were able to determine contributions of each type of constituent chemical bond to the total second-order nlo susceptibility. the tenser values thus calculated are in good agreement with experimental data. from the comparison of nlo tenser coefficients of these two crystals, we found that the major nlo contributors are ko12 groups and lio6 octahedra not the distorted nbo6 octahedra. the difference between their nlo properties arises from their different structural characters, and the high coordination number of constituent elements in knbo3 makes its valence electrons become more delocalised compared with those of linbo3. (c) 1997 elsevier science ltd. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-22 ; 2011-06-09 |
源URL | [http://ir.ciac.jl.cn/handle/322003/24031] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Xue DF,Zhang SY. Comparison of non-linear optical susceptibilities of KNbO3 and LiNbO3[J]. journal of physics and chemistry of solids,1997,58(9):1399-1402. |
APA | Xue DF,&Zhang SY.(1997).Comparison of non-linear optical susceptibilities of KNbO3 and LiNbO3.journal of physics and chemistry of solids,58(9),1399-1402. |
MLA | Xue DF,et al."Comparison of non-linear optical susceptibilities of KNbO3 and LiNbO3".journal of physics and chemistry of solids 58.9(1997):1399-1402. |
入库方式: OAI收割
来源:长春应用化学研究所
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