Ion-conducting polymers based on modified alternating maleic anhydride copolymer with oligo(oxyethylene) side chains
文献类型：期刊论文
| 作者 | Ding LM ; Shi J ; Yang CZ |
| 刊名 | synthetic metals
 |
| 出版日期 | 1997 |
| 卷号 | 87期号:2页码:157-163 |
| 关键词 | SOLID ELECTROLYTES SALT MIXTURES POLY(ETHYLENE OXIDE) LITHIUM PERCHLORATE COMB POLYMERS TRANSPORT ITACONATE) COMPLEXES LICLO4 |
| ISSN号 | 0379-6779 |
| 通讯作者 | ding lm |
| 中文摘要 | comb-like polymers (cps) based on modified alternating methyl vinyl ether/maleic anhydride copolymer with oligo(oxyethylene) side chains of the type -o(ch2ch2o)(n)ch3 were synthesized and characterized, and complexed with lithium salts to form amorphous polymer electrolytes. maximum conductivity close to 1.38 x 10(-4) s/cm was achieved at room temperature and at a [li]/[eo] ratio (eo = ethylene oxide) of about 0.066. the temperature dependence of ionic conductivity suggested that the ion transport was controlled by segmental motion of the polymer, shown by linear curves obtained in vogel-tammann-fulcher plots. the ionic conductivity maximum moved to a higher salt concentration as the temperature increased, indicating that a larger number of charge carriers can be transferred through polymer chains, of which free volume is increased at higher temperature. ir results indicated that the ester in cps might decompose at 140 degrees c and reproduce the maleic anhydride ring. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/24207]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ding LM,Shi J,Yang CZ. Ion-conducting polymers based on modified alternating maleic anhydride copolymer with oligo(oxyethylene) side chains[J]. synthetic metals,1997,87(2):157-163. |
| APA | Ding LM,Shi J,&Yang CZ.(1997).Ion-conducting polymers based on modified alternating maleic anhydride copolymer with oligo(oxyethylene) side chains.synthetic metals,87(2),157-163. |
| MLA | Ding LM,et al."Ion-conducting polymers based on modified alternating maleic anhydride copolymer with oligo(oxyethylene) side chains".synthetic metals 87.2(1997):157-163. |
入库方式： OAI收割
来源：长春应用化学研究所
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