The synthesis and thermotropic liquid crystalline behavior of the novel poly(aryl ether ketone)s containing chloro-side group
文献类型:期刊论文
作者 | Zhang SJ ; Zheng YB ; Wu ZW ; Tian MW ; Yang DC ; Yosomiya R |
刊名 | polymer bulletin
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出版日期 | 1997 |
卷号 | 38期号:6页码:621-625 |
关键词 | POLYMERS |
ISSN号 | 0170-0839 |
中文摘要 | the novel poly(aryl ether ketone)s containing chloro-side group were synthesized by nucleophilic substitution reactions of 4,4'-biphenol and chlorohydroquinone with either 4,4'-difluorobenzophenone(bp/ch/df) or 1,4-bis(p-fluorobenzoyl)benzene (bp/ch/bf) and their thermotropic liquid crystalline properties were characterized by a variety of experimental techniques. the thermotropic liquid crystalline behavior was observed in the copolymers containing 50 and 70% biphenol. melting transition (tm) and isotropization transition (ti) both appeared in the dsc thermograms. a banded texture was formed after shearing the sample in the liquid crystalline state. the novel poly(aryl ether ketone)s had relatively higher glass transition temperature (tg) in the range of 168 similar to 200 degrees c and lower melting temperature (tm) in the range of 290 similar to 340 degrees c. the thermal stability (td) was in the range of 430 similar to 490 degrees c. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-22 ; 2011-06-09 |
源URL | [http://ir.ciac.jl.cn/handle/322003/24235] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Zhang SJ,Zheng YB,Wu ZW,et al. The synthesis and thermotropic liquid crystalline behavior of the novel poly(aryl ether ketone)s containing chloro-side group[J]. polymer bulletin,1997,38(6):621-625. |
APA | Zhang SJ,Zheng YB,Wu ZW,Tian MW,Yang DC,&Yosomiya R.(1997).The synthesis and thermotropic liquid crystalline behavior of the novel poly(aryl ether ketone)s containing chloro-side group.polymer bulletin,38(6),621-625. |
MLA | Zhang SJ,et al."The synthesis and thermotropic liquid crystalline behavior of the novel poly(aryl ether ketone)s containing chloro-side group".polymer bulletin 38.6(1997):621-625. |
入库方式: OAI收割
来源:长春应用化学研究所
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