Crystallization behavior of blends of high-density polyethylene with novel linear low-density polyethylene
文献类型：期刊论文
| 作者 | Zhao Y ; Liu SS ; Yang DC |
| 刊名 | macromolecular chemistry and physics
 |
| 出版日期 | 1997 |
| 卷号 | 198期号:5页码:1427-1436 |
| 关键词 | LIQUID-PHASE-SEPARATION ANGLE LIGHT-SCATTERING BRANCHED POLYETHYLENE SEGREGATION COCRYSTALLIZATION MORPHOLOGY MELTS MODEL |
| ISSN号 | 1022-1352 |
| 中文摘要 | blends of high-density polyethylene (hdpe) with novel linear low-density polyethylene (lldpe) samples in the whole range of compositions were investigated by means of differential scanning calorimetry (dsc), small-angle x-ray scattering (saxs) and wide-angle x-ray diffraction (waxd). the lldpes are ethylene/octene-1 copolymers prepared with a single-site catalyst, with a narrower distribution of branches compared to ziegler-natta type polymers. it was found that cocrystallization or separate crystallization in the blends profoundly depends on the content of branches in the lldpe, while the critical branch content of the novel lldpe for separate crystallization is much lower than that of commercial lldpe (prepared with ziegler-natta catalysts). this implies that the miscibility of linear and branched polyethylene is also affected by the distribution of branches. the marked expansion of the unit cell in cocrystals, which are formed by hdpe with the novel lldpe, indicates that the branches are included in the crystal lattice during the cocrystallization process. the result is very helpful to understand the phenomenon that the unit cell dimensions of commercial branched polyethylene are larger than those of linear polyethylene. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/24251]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhao Y,Liu SS,Yang DC. Crystallization behavior of blends of high-density polyethylene with novel linear low-density polyethylene[J]. macromolecular chemistry and physics,1997,198(5):1427-1436. |
| APA | Zhao Y,Liu SS,&Yang DC.(1997).Crystallization behavior of blends of high-density polyethylene with novel linear low-density polyethylene.macromolecular chemistry and physics,198(5),1427-1436. |
| MLA | Zhao Y,et al."Crystallization behavior of blends of high-density polyethylene with novel linear low-density polyethylene".macromolecular chemistry and physics 198.5(1997):1427-1436. |
入库方式： OAI收割
来源：长春应用化学研究所
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