H-1 nmr study on the ring opening selectivity of aromatic dianhydrides towards methanol
文献类型:期刊论文
作者 | Huang WX ; Gao LX ; Yang ZH ; Zhang X ; Xu JP ; Ding MX |
刊名 | polymer
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出版日期 | 1997 |
卷号 | 38期号:9页码:2033-2039 |
关键词 | IMIDIZATION ACIDS |
ISSN号 | 0032-3861 |
中文摘要 | several isomeric aromatic diester-diacids may appear as a result of the opening selectivity of anhydride groups towards the alcohol. h-1 n.m.r. was thus used to characterize the isomeric structure and to quantify the isomer composition. it was found that the isomer ratios quantitatively correlate with electron affinity of bridged dianhydrides and is independent of the alcohol structure used. furthermore, the h-1 n.m.r chemical shift of bridged diester-diacids was found to be a very sensitive probe of chemical nature of bridged groups and can be used as indices of the opening selectivity. (c) 1997 elsevier science ltd. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-22 |
源URL | [http://ir.ciac.jl.cn/handle/322003/24311] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Huang WX,Gao LX,Yang ZH,et al. H-1 nmr study on the ring opening selectivity of aromatic dianhydrides towards methanol[J]. polymer,1997,38(9):2033-2039. |
APA | Huang WX,Gao LX,Yang ZH,Zhang X,Xu JP,&Ding MX.(1997).H-1 nmr study on the ring opening selectivity of aromatic dianhydrides towards methanol.polymer,38(9),2033-2039. |
MLA | Huang WX,et al."H-1 nmr study on the ring opening selectivity of aromatic dianhydrides towards methanol".polymer 38.9(1997):2033-2039. |
入库方式: OAI收割
来源:长春应用化学研究所
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