Electrochemical study of the interfacial characteristics of redox-active viologen thiol self-assembled monolayers
文献类型：期刊论文
| 作者 | Li JH ; Cheng GJ ; Dong SJ |
| 刊名 | thin solid films
 |
| 出版日期 | 1997 |
| 卷号 | 293期号:1-2页码:200-205 |
| 关键词 | QUASI-REVERSIBLE REACTION ELECTRON-TRANSFER FARADAIC IMPEDANCE AC POLAROGRAPHY GOLD SURFACES KINETICS FILMS ISOTHERM CENTERS SYSTEMS |
| ISSN号 | 0040-6090 |
| 中文摘要 | the electrochemical behavior of the electroactive self-assembled monolayers (sams) of thiol-functionalized viologen, ch3(ch2)(9)v2+(ch2)(8)sh, where v2+ is a viologen group, on the gold electrodes is examined by cyclic voltammetry and electrochemical a.c. impedance. a monolayer of viologen is immobilized on the gold electrode surface via the au-s bond and the normal potentials corresponding to the two successive one-electron transfer processes of the viologen active centers are -310 mv and -652 mv (vs. ag/agcl) in 0.1 mol l(-1) phosphate buffer solution (ph 6.96) respectively. these results suggest that the viologen sams are stable and well-behaved monolayers. the experimental impedance data corresponding to different forms of viologen group have been fitted to equivalent electrical circuits, and the surface capacitances and resistances have been given. the heterogenous electron transfer rates of the first and the second redox processes are 7.57 s(-1) and 1.49 s(-1) respectively through a.c. impedance. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/24325]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li JH,Cheng GJ,Dong SJ. Electrochemical study of the interfacial characteristics of redox-active viologen thiol self-assembled monolayers[J]. thin solid films,1997,293(1-2):200-205. |
| APA | Li JH,Cheng GJ,&Dong SJ.(1997).Electrochemical study of the interfacial characteristics of redox-active viologen thiol self-assembled monolayers.thin solid films,293(1-2),200-205. |
| MLA | Li JH,et al."Electrochemical study of the interfacial characteristics of redox-active viologen thiol self-assembled monolayers".thin solid films 293.1-2(1997):200-205. |
入库方式： OAI收割
来源：长春应用化学研究所
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