Study of ion solvation and ion association in polymer gel electrolyte with polyethylene oxide-co-polypropylene oxide as a plasticizer
文献类型：期刊论文
| 作者 | Sun XG ; Li B ; Lin YQ ; Jing XB |
| 刊名 | polymer international
 |
| 出版日期 | 1996 |
| 卷号 | 41期号:3页码:301-305 |
| 关键词 | LITHIUM PERCHLORATE POLY(PROPYLENE OXIDE) CONDUCTIVITY TEMPERATURE COMPLEXES LICLO4 |
| ISSN号 | 0959-8103 |
| 通讯作者 | sun xg |
| 中文摘要 | using a molal conductance method, ion solvation and ion association in polytriethylene glycol dimethacrylate (ptregd)-liclo4 gel electrolytes with amorphous ethylene oxide-co-propylene oxide (eo-co-po, <(m)over bar (n)>, = 1750) as the plasticizer were investigated. it was found that the fraction of solute existing as single ions (alpha(i)) and ion pairs (alpha(p)) decreases, while that of triple ions (alpha(t)) increases linearly with increasing salt concentration. the dependence of these fractions on molecular weight of plasticizer was also examined. it was shown that alpha(i) and alpha(t) increase and alpha(p) decreases with increasing molecular weight. the result of temperature dependence of these fractions was very interesting: when the temperature is lower than 55 degrees c, alpha(i) increases while alpha(p) and alpha(t) decrease with increasing temperature; however, when the temperature is higher than 55 degrees c, the reverse is true. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/25169]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Sun XG,Li B,Lin YQ,et al. Study of ion solvation and ion association in polymer gel electrolyte with polyethylene oxide-co-polypropylene oxide as a plasticizer[J]. polymer international,1996,41(3):301-305. |
| APA | Sun XG,Li B,Lin YQ,&Jing XB.(1996).Study of ion solvation and ion association in polymer gel electrolyte with polyethylene oxide-co-polypropylene oxide as a plasticizer.polymer international,41(3),301-305. |
| MLA | Sun XG,et al."Study of ion solvation and ion association in polymer gel electrolyte with polyethylene oxide-co-polypropylene oxide as a plasticizer".polymer international 41.3(1996):301-305. |
入库方式： OAI收割
来源：长春应用化学研究所
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