Efficient cleavage of ribonucleoside 3',5'-cyclic phosphates and deoxyribonucleoside 3',5'-cyclic phosphate by lanthanides
文献类型：期刊论文
| 作者 | Li XM ; Zhu B ; Zhao DQ ; Ni JZ |
| 刊名 | indian journal of chemistry section b-organic chemistry including medicinal chemistry
 |
| 出版日期 | 1996 |
| 卷号 | 35期号:11页码:1144-1147 |
| 关键词 | MOLECULAR-OXYGEN DNA HYDROLYSIS CERIUM(III) COMPLEXES RNA |
| ISSN号 | 0376-4699 |
| 通讯作者 | li xm |
| 中文摘要 | the cleavage of 3',5'-camp, 3',5'-cgmp and 3',5'-dcamp by lanthanides has been investigated by hplc and h-1 nmr. rapid cleavage of camp, cgmp and dcamp by ce(iii) under air at ph 8 and 37 degrees c has been observed. regioselective cleavage of p-o(5') bond in camp, cgmp and dc;amp tu give the corresponding 3'-amp, 3'-gmp and 3'-damp by lanthanide chlorides has been achieved, and 3'-amp and 3'-gmp are cleaved to adenosine(a) and guanosine(ct) more slowly, respectively, the notable difference in reactivity between ce(iii) and the other lanthanide ions under air has also been studied. the cleavage is enhanced with the increase in the molar fraction of ce(iv). the fast cleavage of camp by ce(iii) under air at ph 8 is ascribed to the resultant ce(iv) in the reaction mixture. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/25191]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li XM,Zhu B,Zhao DQ,et al. Efficient cleavage of ribonucleoside 3',5'-cyclic phosphates and deoxyribonucleoside 3',5'-cyclic phosphate by lanthanides[J]. indian journal of chemistry section b-organic chemistry including medicinal chemistry,1996,35(11):1144-1147. |
| APA | Li XM,Zhu B,Zhao DQ,&Ni JZ.(1996).Efficient cleavage of ribonucleoside 3',5'-cyclic phosphates and deoxyribonucleoside 3',5'-cyclic phosphate by lanthanides.indian journal of chemistry section b-organic chemistry including medicinal chemistry,35(11),1144-1147. |
| MLA | Li XM,et al."Efficient cleavage of ribonucleoside 3',5'-cyclic phosphates and deoxyribonucleoside 3',5'-cyclic phosphate by lanthanides".indian journal of chemistry section b-organic chemistry including medicinal chemistry 35.11(1996):1144-1147. |
入库方式： OAI收割
来源：长春应用化学研究所
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