Synthesis and chemical properties of [Z]-1-[2-(triaryl stannyl)vinyl]cyclooctanol
文献类型:期刊论文
作者 | Ren YJ ; Fu FX ; Zhu DS ; Pan HD ; Jing FY |
刊名 | acta chimica sinica
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出版日期 | 1996 |
卷号 | 54期号:9页码:929-936 |
ISSN号 | 0567-7351 |
通讯作者 | ren yj |
中文摘要 | the compounds of [z]-1-[2-(triphenyl stannyl) vinyl] cyclooctanol (1) and [z]-1-[2-(tri-p-tolyl stannyl) vinyl] cyclooctanol (2) were synthesized by the reactions of triphenyltin hydride and tri-p-tolyltin hydride with 1-ethynyl cyclooctanol. the crystal structure of compound 1 was determined. the reactions of compound 1 and 2 with ic1, br-2, i-2 formed nine organotin halides. the organotin oxide or hydroxide were prepared by the reactions of [z]-1-[2-(phenyl dibromo stannyl) vinyl] cyclooctanol (6) and [z]-1-[2-(diphenyl monobromo stannyl) vinyl] cyclooctanol (5) with koh. three complexes were obtained by the reactions of [z]-1-[2-(phenyl diiodide stannyl) vinyl] cyclooctanol (8) with three ligands (2,2'-bipyridyl,5-nitro-1,10-phenanthroline,8-hydroxyquinoline). the sixteen new compounds synthesized in this paper were characterized by means of elemental analysis, ir, h-1 nmr. the reaction mechanism of triphenyltin hydride and tri-p-tolyltin hydride with 1-ethynyl cyclooctanol were also proposed. |
收录类别 | SCI收录期刊论文 |
语种 | japanese |
公开日期 | 2010-12-22 ; 2011-06-09 |
源URL | [http://ir.ciac.jl.cn/handle/322003/25193] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Ren YJ,Fu FX,Zhu DS,et al. Synthesis and chemical properties of [Z]-1-[2-(triaryl stannyl)vinyl]cyclooctanol[J]. acta chimica sinica,1996,54(9):929-936. |
APA | Ren YJ,Fu FX,Zhu DS,Pan HD,&Jing FY.(1996).Synthesis and chemical properties of [Z]-1-[2-(triaryl stannyl)vinyl]cyclooctanol.acta chimica sinica,54(9),929-936. |
MLA | Ren YJ,et al."Synthesis and chemical properties of [Z]-1-[2-(triaryl stannyl)vinyl]cyclooctanol".acta chimica sinica 54.9(1996):929-936. |
入库方式: OAI收割
来源:长春应用化学研究所
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