中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes

文献类型:期刊论文

作者Zhou HF ; Dong SJ
刊名journal of electroanalytical chemistry
出版日期1996
卷号414期号:2页码:121-125
ISSN号0022-0728
关键词SOLID-STATE VOLTAMMETRY ELECTROACTIVE SOLUTES MICRODISK ELECTRODES TRANSPORT CHRONOAMPEROMETRY MICROELECTRODES COEFFICIENTS TEMPERATURE SOLVENTS FILMS
中文摘要the diffusion rates of ferrocene have been estimated in five kinds of poly(ethylene glycol) solution, containing the electrolyte liclo4, by using non-steady-state chronoamperometry. the d-app of ferrocene increases with increasing temperature, and the dependency of d-app on temperature obeys the williams-landel-ferry equation. the d-app of ferrocene decreases with increasing polymer chain length. both the chain length and temperature dependence conform to a simple free volume model. a relation between current and polymer chain length is suggested at room and high temperatures.
收录类别SCI收录期刊论文
语种英语
公开日期2010-12-22 ; 2011-06-09
源URL[http://ir.ciac.jl.cn/handle/322003/25199]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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GB/T 7714
Zhou HF,Dong SJ. A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes[J]. journal of electroanalytical chemistry,1996,414(2):121-125.
APA Zhou HF,&Dong SJ.(1996).A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes.journal of electroanalytical chemistry,414(2),121-125.
MLA Zhou HF,et al."A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes".journal of electroanalytical chemistry 414.2(1996):121-125.

入库方式: OAI收割

来源:长春应用化学研究所

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