A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes
文献类型:期刊论文
| 作者 | Zhou HF ; Dong SJ |
| 刊名 | journal of electroanalytical chemistry
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| 出版日期 | 1996 |
| 卷号 | 414期号:2页码:121-125 |
| 关键词 | SOLID-STATE VOLTAMMETRY ELECTROACTIVE SOLUTES MICRODISK ELECTRODES TRANSPORT CHRONOAMPEROMETRY MICROELECTRODES COEFFICIENTS TEMPERATURE SOLVENTS FILMS |
| ISSN号 | 0022-0728 |
| 中文摘要 | the diffusion rates of ferrocene have been estimated in five kinds of poly(ethylene glycol) solution, containing the electrolyte liclo4, by using non-steady-state chronoamperometry. the d-app of ferrocene increases with increasing temperature, and the dependency of d-app on temperature obeys the williams-landel-ferry equation. the d-app of ferrocene decreases with increasing polymer chain length. both the chain length and temperature dependence conform to a simple free volume model. a relation between current and polymer chain length is suggested at room and high temperatures. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/25199] ![]() |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Zhou HF,Dong SJ. A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes[J]. journal of electroanalytical chemistry,1996,414(2):121-125. |
| APA | Zhou HF,&Dong SJ.(1996).A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes.journal of electroanalytical chemistry,414(2),121-125. |
| MLA | Zhou HF,et al."A study of the dependence of ferrocene diffusion on chain length in polymer electrolytes".journal of electroanalytical chemistry 414.2(1996):121-125. |
入库方式: OAI收割
来源:长春应用化学研究所
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