Miscibility of linear low density polyethylene (LLDPE)-graft-poly(methyl methacrylate) with poly(vinylidene fluoride) (PVF2) and its application as compatibilizer LLDPE/PVF2 blends
文献类型:期刊论文
作者 | Li L ; Tang T ; Huang BT |
刊名 | angewandte makromolekulare chemie
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出版日期 | 1996 |
卷号 | 241页码:77-93 |
关键词 | POLY(METHYL METHACRYLATE) PHASE-SEPARATION BLOCK COPOLYMER POLYMER BLENDS CRYSTALLIZATION BEHAVIOR STYRENE OXIDE) POLYSTYRENE HOMOPOLYMER |
ISSN号 | 0003-3146 |
中文摘要 | differential scanning calorimetry (dsc), fourier-transform infrared spectroscopy (ftir), scanning electron microscopy (sem), and x-ray photoelectron spectroscopy (xps) were used to study the miscibility of blends of a graft copolymer of poly(methyl methacrylate) on linear low density polyethylene (lldpe-g-pmma, g-3) with poly(vinylidene fluoride)(b) (pvf2) and the compatibilization of blends of lldpe/pvf2. the specific interaction between pmma side chains and pvf2 in g-3/pvf2 binary blends is weaker than that between the homopolymers pmma and pvf2. there are two states of pvf2 in the melt of a g-3/pvf2 (60/40, w/w) blend, one as pure pvf2 and the other interacting with pmma side chains. the miscibility between pmma side chains and pvf2 affects the crystallization of pvf2. lldpe-g-pmma was demonstrated to be a good compatibilizer in lldpe/pvf2 blends, improving the interfacial adhesion and dispersion in the latter. diffusion of pmma side chains into pvf2 in the interfacial region reduces the crystallization rate and lowers the melting point (t-m) and the crystallization temperature (t-c) of pvf2 in the blends. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-22 ; 2011-06-09 |
源URL | [http://ir.ciac.jl.cn/handle/322003/25201] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Li L,Tang T,Huang BT. Miscibility of linear low density polyethylene (LLDPE)-graft-poly(methyl methacrylate) with poly(vinylidene fluoride) (PVF2) and its application as compatibilizer LLDPE/PVF2 blends[J]. angewandte makromolekulare chemie,1996,241:77-93. |
APA | Li L,Tang T,&Huang BT.(1996).Miscibility of linear low density polyethylene (LLDPE)-graft-poly(methyl methacrylate) with poly(vinylidene fluoride) (PVF2) and its application as compatibilizer LLDPE/PVF2 blends.angewandte makromolekulare chemie,241,77-93. |
MLA | Li L,et al."Miscibility of linear low density polyethylene (LLDPE)-graft-poly(methyl methacrylate) with poly(vinylidene fluoride) (PVF2) and its application as compatibilizer LLDPE/PVF2 blends".angewandte makromolekulare chemie 241(1996):77-93. |
入库方式: OAI收割
来源:长春应用化学研究所
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