中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Miscibility of linear low density polyethylene (LLDPE)-graft-poly(methyl methacrylate) with poly(vinylidene fluoride) (PVF2) and its application as compatibilizer LLDPE/PVF2 blends

文献类型:期刊论文

作者Li L ; Tang T ; Huang BT
刊名angewandte makromolekulare chemie
出版日期1996
卷号241页码:77-93
关键词POLY(METHYL METHACRYLATE) PHASE-SEPARATION BLOCK COPOLYMER POLYMER BLENDS CRYSTALLIZATION BEHAVIOR STYRENE OXIDE) POLYSTYRENE HOMOPOLYMER
ISSN号0003-3146
中文摘要differential scanning calorimetry (dsc), fourier-transform infrared spectroscopy (ftir), scanning electron microscopy (sem), and x-ray photoelectron spectroscopy (xps) were used to study the miscibility of blends of a graft copolymer of poly(methyl methacrylate) on linear low density polyethylene (lldpe-g-pmma, g-3) with poly(vinylidene fluoride)(b) (pvf2) and the compatibilization of blends of lldpe/pvf2. the specific interaction between pmma side chains and pvf2 in g-3/pvf2 binary blends is weaker than that between the homopolymers pmma and pvf2. there are two states of pvf2 in the melt of a g-3/pvf2 (60/40, w/w) blend, one as pure pvf2 and the other interacting with pmma side chains. the miscibility between pmma side chains and pvf2 affects the crystallization of pvf2. lldpe-g-pmma was demonstrated to be a good compatibilizer in lldpe/pvf2 blends, improving the interfacial adhesion and dispersion in the latter. diffusion of pmma side chains into pvf2 in the interfacial region reduces the crystallization rate and lowers the melting point (t-m) and the crystallization temperature (t-c) of pvf2 in the blends.
收录类别SCI收录期刊论文
语种英语
公开日期2010-12-22 ; 2011-06-09
源URL[http://ir.ciac.jl.cn/handle/322003/25201]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
Li L,Tang T,Huang BT. Miscibility of linear low density polyethylene (LLDPE)-graft-poly(methyl methacrylate) with poly(vinylidene fluoride) (PVF2) and its application as compatibilizer LLDPE/PVF2 blends[J]. angewandte makromolekulare chemie,1996,241:77-93.
APA Li L,Tang T,&Huang BT.(1996).Miscibility of linear low density polyethylene (LLDPE)-graft-poly(methyl methacrylate) with poly(vinylidene fluoride) (PVF2) and its application as compatibilizer LLDPE/PVF2 blends.angewandte makromolekulare chemie,241,77-93.
MLA Li L,et al."Miscibility of linear low density polyethylene (LLDPE)-graft-poly(methyl methacrylate) with poly(vinylidene fluoride) (PVF2) and its application as compatibilizer LLDPE/PVF2 blends".angewandte makromolekulare chemie 241(1996):77-93.

入库方式: OAI收割

来源:长春应用化学研究所

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