Phenol hydroxylation by iron(II) phenanthroline: The reaction mechanism
文献类型：期刊论文
| 作者 | Liu CB ; Ye XK ; Zhan RY ; Wu Y |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 1996 |
| 卷号 | 112期号:1页码:15-22 |
| 关键词 | HYDROGEN-PEROXIDE TITANIUM SILICALITE OXIDATION COMPLEXES |
| ISSN号 | 1381-1169 |
| 中文摘要 | phenol hydroxylation catalyzed by iron(ii)-1,10-phenanthroline is investigated through kinetics, esr, w-vis as well as cyclic voltammogram studies. the optimum reaction conditions are obtained for diphenols production. radical substitution mechanism is first proposed to explain the effects of ph, reaction medium and other factors on the phenol hydroxylation with h2o2 as oxidant, and found that the coexisting of iron(ii)-1,10-phenanthroline and iron(iii)-1,10-phenanthroline is the key for phenol hydroxylation to occur with h2o2 as oxygen donor. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:A1996VM67500003 |
| 公开日期 | 2010-12-22 |
| 源URL | [http://202.98.16.49/handle/322003/25203]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu CB,Ye XK,Zhan RY,et al. Phenol hydroxylation by iron(II) phenanthroline: The reaction mechanism[J]. journal of molecular catalysis a-chemical,1996,112(1):15-22. |
| APA | Liu CB,Ye XK,Zhan RY,&Wu Y.(1996).Phenol hydroxylation by iron(II) phenanthroline: The reaction mechanism.journal of molecular catalysis a-chemical,112(1),15-22. |
| MLA | Liu CB,et al."Phenol hydroxylation by iron(II) phenanthroline: The reaction mechanism".journal of molecular catalysis a-chemical 112.1(1996):15-22. |
入库方式： OAI收割
来源：长春应用化学研究所
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