Syntheses and reactions of heterometallic complexes of nickel and copper with tetrathiotungstates. The molecular structures of [Ph(4)P](2)[S2W(mu-S)(2)Ni(S-2)] and W(mu-S)(4)Cu-2(PPh(3))(4)center dot py
文献类型：期刊论文
| 作者 | Jin GX ; Xin QX ; Wang BY |
| 刊名 | zeitschrift fur naturforschung section b-a journal of chemical sciences
 |
| 出版日期 | 1996 |
| 卷号 | 51期号:8页码:1197-1203 |
| 关键词 | CRYSTAL-STRUCTURES MO-S METAL THIOMOLYBDATES THIOTUNGSTATES CHEMISTRY ANIONS |
| ISSN号 | 0932-0776 |
| 通讯作者 | jin gx |
| 中文摘要 | reaction of [ph(4)p]2ws4 with nicl2 in methanol solution in the presence of naoch3 leads to the formation of [ph(4)p](2) [s2w(mu-s)(2)ni(s-2)] (i) a similar reaction between (nh4)(2)ws4 and nicl2 under o-2 atmosphere in the presence of ph(4)pcl or (n)bu(4)ncl affords [ph(4)p](2)([(s-2)w(o)(mu-s)(2)]ni-2] (iia) and [(n)bu(4)n](2)([(s-2)w(o)(mu-s)(2)]ni-2} (iib) under argon the same reaction gives [ph(4)p](2)[ni(ws4)(2)] (iiia) and [(n)bu(4)n](2)[ni(ws4)(2)] (iiib). [ph(4)p](2)[ni(wos3)(2)] (iv) and [ph(4)p](2)[ni(wo2s2)(2)] (v) can be prepared from the reaction of [ph(4)p]2wos3 and [ph(4)p]2wo2s2 with nicl2. treatment of (nh4)(2)ws4 with cucl in the presence of pph(3) in boiling pyridine produces w(mu-s)(4)cu-2(pph(3))(3) (vi), which can further react with excess pph(3) to give w(mu-s)(4)cu-2(pph(3))(4) . py (vii). complex i crystallizes in the space group p2(1)/n with the cell parameters: a = 20.049(4), b = 17.010(4), c = 14.311(7) angstrom; beta = 110.24(3)degrees and z = 4; r = 0.058 for 4267 independent reflections. the structural study confirms that complex i contains two terminal sulfide ligands, two bridging sulfide ligands, a side-on disulfide ligand, and a planar central w(mu-s)(2)ni four membered ring. complex vii crystallizes in the space group c2/c with the cell parameters: a = 26.436(8), b = 20.542(6), c = 19.095(8) angstrom; beta = 125.00(3)degrees and z = 4; r = 0.080 for 3802 independent reflections. the structural study reveals a perfect linear arrangement of the three metal atoms cu-w-cu. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/25263]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Jin GX,Xin QX,Wang BY. Syntheses and reactions of heterometallic complexes of nickel and copper with tetrathiotungstates. The molecular structures of [Ph(4)P](2)[S2W(mu-S)(2)Ni(S-2)] and W(mu-S)(4)Cu-2(PPh(3))(4)center dot py[J]. zeitschrift fur naturforschung section b-a journal of chemical sciences,1996,51(8):1197-1203. |
| APA | Jin GX,Xin QX,&Wang BY.(1996).Syntheses and reactions of heterometallic complexes of nickel and copper with tetrathiotungstates. The molecular structures of [Ph(4)P](2)[S2W(mu-S)(2)Ni(S-2)] and W(mu-S)(4)Cu-2(PPh(3))(4)center dot py.zeitschrift fur naturforschung section b-a journal of chemical sciences,51(8),1197-1203. |
| MLA | Jin GX,et al."Syntheses and reactions of heterometallic complexes of nickel and copper with tetrathiotungstates. The molecular structures of [Ph(4)P](2)[S2W(mu-S)(2)Ni(S-2)] and W(mu-S)(4)Cu-2(PPh(3))(4)center dot py".zeitschrift fur naturforschung section b-a journal of chemical sciences 51.8(1996):1197-1203. |
入库方式： OAI收割
来源：长春应用化学研究所
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