Mass spectrometric evidence for the generation of benzyne from benzoyl peroxide in thermolysis
文献类型：期刊论文
| 作者 | Tu YP ; Yuan HS ; Liu SY |
| 刊名 | rapid communications in mass spectrometry
 |
| 出版日期 | 1996 |
| 卷号 | 10期号:9页码:1093-1095 |
| 关键词 | IONIZATION |
| ISSN号 | 0951-4198 |
| 通讯作者 | tu yp |
| 中文摘要 | benzoyl peroxide gave rise to benzoic acid (at m/z 122) in its electron impact mass spectrum, and its perdeuterated counterpart produced perdeuterobenzoic acid, c6d5co2d, at m/z 128 under the same conditions, an intramolecular hydrogen abstraction is proposed for the formation of benzoic acid from the peroxide in thermolysis. as a result of this reaction, benzyne would be generated simultaneously. anthracene was employed to trap any of the reactive intermediate benzyne. collision-induced dissociation of the ion of m/z 254 from the mixture of benzoyl peroxide and anthracene indicated that triptycene was obtained by the trapping reaction, therefore confirming that benzyne is generated from benzoyl peroxide in thermolysis. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/25367]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Tu YP,Yuan HS,Liu SY. Mass spectrometric evidence for the generation of benzyne from benzoyl peroxide in thermolysis[J]. rapid communications in mass spectrometry,1996,10(9):1093-1095. |
| APA | Tu YP,Yuan HS,&Liu SY.(1996).Mass spectrometric evidence for the generation of benzyne from benzoyl peroxide in thermolysis.rapid communications in mass spectrometry,10(9),1093-1095. |
| MLA | Tu YP,et al."Mass spectrometric evidence for the generation of benzyne from benzoyl peroxide in thermolysis".rapid communications in mass spectrometry 10.9(1996):1093-1095. |
入库方式： OAI收割
来源：长春应用化学研究所
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