Improvements in the selectivity of electrochemical detectors for liquid chromatography and flow injection analysis using the self-assembled n-alkanethiol monolayer-modified au electrode
文献类型：期刊论文
| 作者 | Liu ZM ; Li JH ; Dong SJ ; Wang EK |
| 刊名 | analytical chemistry
 |
| 出版日期 | 1996 |
| 卷号 | 68期号:14页码:2432-2436 |
| 关键词 | ORGANIZED MOLECULAR ASSEMBLIES STRUCTURAL CHARACTERIZATION THIOL MONOLAYERS GOLD ELECTRODES STREAMS SURFACE FILM |
| ISSN号 | 0003-2700 |
| 中文摘要 | 4-aminophenol (4-ap), paracetamol (prct), norepinephrine (ne), and dopamine (da) (all somewhat hydrophobic compounds) were hplc electrochemically detected while the signals from uric acid (ua) and ascorbic acid (aa) (both hydrophilic compounds at the ph studied) were minimized, taking advantage of the permselectivity of the self-assembled n-alkanethiol monolayer (c-10-sam)-modified au electrodes based on solute polarity, the effects of various factors, such as the chain length of the n-alkanethiol modifier, modifying time, and ph value, on the permeability of c-10-sam coatings were examined, the calibration curves, linear response ranges, detection limits, and reproducibilities of the ec detector for 4-ap, prct, ne, and da were obtained, the result shows that the ec detector can be applied in the chromatographic detection of 4-ap, prct, ne, and da in urine, effectively removing the influence of ua and aa in high concentrations existing in biological samples. as a result, a great improvement in the selectivity of ec detectors has been achieved by using au electrodes coated with neutral n-alkanethiol monolayer. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/25379]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Liu ZM,Li JH,Dong SJ,et al. Improvements in the selectivity of electrochemical detectors for liquid chromatography and flow injection analysis using the self-assembled n-alkanethiol monolayer-modified au electrode[J]. analytical chemistry,1996,68(14):2432-2436. |
| APA | Liu ZM,Li JH,Dong SJ,&Wang EK.(1996).Improvements in the selectivity of electrochemical detectors for liquid chromatography and flow injection analysis using the self-assembled n-alkanethiol monolayer-modified au electrode.analytical chemistry,68(14),2432-2436. |
| MLA | Liu ZM,et al."Improvements in the selectivity of electrochemical detectors for liquid chromatography and flow injection analysis using the self-assembled n-alkanethiol monolayer-modified au electrode".analytical chemistry 68.14(1996):2432-2436. |
入库方式： OAI收割
来源：长春应用化学研究所
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