Laser light-scattering study of novel thermoplastics .2. Phenolphthalein poly(ether sulfone) (PES-C)
文献类型：期刊论文
| 作者 | Wu C ; Siddiq M ; Bo SQ ; Chen TL |
| 刊名 | macromolecules
 |
| 出版日期 | 1996 |
| 卷号 | 29期号:9页码:3157-3160 |
| ISSN号 | 0024-9297 |
| 通讯作者 | wu c |
| 中文摘要 | five narrowly distributed fractions of phenolphthalein poly(ether sulfone) (pes-c) were studied in chcl3 by both static and dynamic laser light scattering (lls) at 25 degrees c. the dynamic lls showed that the pes-c samples contain some large polymer clusters as in previously studied phenolphthalein poly(ether ketone)(pek-c). these large clusters can be removed by a 0.1-mu m filter. our results showed that [r(g)(2)](1/2)(z) = (3.35 +/- 0.13) x 10(-2) m(w)((0.52 +/- 0.03)) and [d] = (2.26 +/- 0.02) x 10(-4)m(w)-((0.54) +/- 0.03)) with [r(g)(2)](1/2)(z), m(w) and [d] being the z-average radius of gyration, the weight-average molecular weight, and the z-average translational diffusion coefficient, respectively. a combination of static and dynamic lls results enabled us to determine d = (2.45 +/- 0.04) x 10(-4)m-((0.55 +/- 0.05)), where d and m correspond to monodisperse species. using this scaling relationship, we have successfully converted the translational diffusion coefficient distribution into the molecular weight distribution for each of the five pes-c fractional the weight-average molecular weights obtained from dynamic light scattering have a good agreement with that obtained from static laser light-scattering measurements. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/25485]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wu C,Siddiq M,Bo SQ,et al. Laser light-scattering study of novel thermoplastics .2. Phenolphthalein poly(ether sulfone) (PES-C)[J]. macromolecules,1996,29(9):3157-3160. |
| APA | Wu C,Siddiq M,Bo SQ,&Chen TL.(1996).Laser light-scattering study of novel thermoplastics .2. Phenolphthalein poly(ether sulfone) (PES-C).macromolecules,29(9),3157-3160. |
| MLA | Wu C,et al."Laser light-scattering study of novel thermoplastics .2. Phenolphthalein poly(ether sulfone) (PES-C)".macromolecules 29.9(1996):3157-3160. |
入库方式： OAI收割
来源：长春应用化学研究所
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