The reactivity of lanthanide alkyl compounds with phenylacetylene: Synthesis and structure of [(Bu(t)Cp)(2)LnC CPh](2) (Ln=Nd, Gd)
文献类型：期刊论文
| 作者 | Ren JS ; Hu JY ; Lin YH ; Xing Y ; Shen Q |
| 刊名 | polyhedron
 |
| 出版日期 | 1996 |
| 卷号 | 15期号:13页码:2165-2169 |
| 关键词 | CARBON BOND FORMATION CRYSTALLOGRAPHIC CHARACTERIZATION ORGANOLANTHANIDE COMPLEXES METAL |
| ISSN号 | 0277-5387 |
| 中文摘要 | [(bu(t)cp)(2)lnch(3)](2) (ln = nd, gd) react with phc=ch to form the dimeric alkynide-bridged complexes [(bu(t)cp)(2)lnc=cph](2) [ln = nd (i), gd (ii)]. both compounds crystallized from toluene in the monoclinic space group c2/c. the two complexes are homologous, composed of asymmetric metal-alkynide bridges with nd-c, gd-c (alkynide) bond lengths of 2.602(4), 2.641(5) (i) and 2.532(6), 2.601(7) angstrom (ii), respectively. the average nd-c (ring) and gd-c (ring) distances are 2.746(13) and 2.703(19)angstrom. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/25491]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Ren JS,Hu JY,Lin YH,et al. The reactivity of lanthanide alkyl compounds with phenylacetylene: Synthesis and structure of [(Bu(t)Cp)(2)LnC CPh](2) (Ln=Nd, Gd)[J]. polyhedron,1996,15(13):2165-2169. |
| APA | Ren JS,Hu JY,Lin YH,Xing Y,&Shen Q.(1996).The reactivity of lanthanide alkyl compounds with phenylacetylene: Synthesis and structure of [(Bu(t)Cp)(2)LnC CPh](2) (Ln=Nd, Gd).polyhedron,15(13),2165-2169. |
| MLA | Ren JS,et al."The reactivity of lanthanide alkyl compounds with phenylacetylene: Synthesis and structure of [(Bu(t)Cp)(2)LnC CPh](2) (Ln=Nd, Gd)".polyhedron 15.13(1996):2165-2169. |
入库方式： OAI收割
来源：长春应用化学研究所
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