Laser light-scattering study of novel thermoplastics .1. Phenolphthalein poly(aryl ether ketone)
文献类型：期刊论文
| 作者 | Wu C ; Bo SQ ; Siddiq M ; Yang GJ ; Chen TL |
| 刊名 | macromolecules
 |
| 出版日期 | 1996 |
| 卷号 | 29期号:8页码:2989-2993 |
| ISSN号 | 0024-9297 |
| 通讯作者 | wu c |
| 中文摘要 | five different molecular weight phenolphthalein poly(aryl ether ketone) (pek-c) fractions in chcl3 were studied by static and dynamic laser light scattering(lls). the dynamic lls revealed that the pek-c samples contain some large polymer clusters. these large clusters can be removed by filtering the solution with a 0.1-mu m filter. we found that the persistence length of pek-c in chcl3 at 25 degrees c is similar to 2 nm and the flory characteristic ratio, c-infinity is similar to 25. our results showed that [r(g)(2)](1/2)(z) = (3.50+/-0.20) x 10(-2)m(w)(0.54+/-0.01) and [d] = (2.37+/-0.05) x 10(-4)m(w)(-0.55+/-0.01), with [r(g)(2)](1/2)(z), m(w), and [d] being the z-average radius of gyration, the weight-average molecular weight, and the z-average translational diffusion coefficient, respectively. a combination of static and dynamic lls results enabled us to determine d = (2.20+/-0.10) x 10(-4)m(-0.555+/-0.015), where d and m correspond to monodisperse species. using this calibration between d and m,we have determined molecular weight distributions of five pek-c fractions from their corresponding translational diffusion coefficient distribution. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-22 ; 2011-06-09 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/25517]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Wu C,Bo SQ,Siddiq M,et al. Laser light-scattering study of novel thermoplastics .1. Phenolphthalein poly(aryl ether ketone)[J]. macromolecules,1996,29(8):2989-2993. |
| APA | Wu C,Bo SQ,Siddiq M,Yang GJ,&Chen TL.(1996).Laser light-scattering study of novel thermoplastics .1. Phenolphthalein poly(aryl ether ketone).macromolecules,29(8),2989-2993. |
| MLA | Wu C,et al."Laser light-scattering study of novel thermoplastics .1. Phenolphthalein poly(aryl ether ketone)".macromolecules 29.8(1996):2989-2993. |
入库方式： OAI收割
来源：长春应用化学研究所
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