A comparison of electrocatalytic ability of various mediators adsorbed onto paraffin impregnated graphite electrodes for oxidation of reduced nicotinamide coenzymes
文献类型:期刊论文
作者 | Chi QJ ; Dong SJ |
刊名 | journal of molecular catalysis a-chemical
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出版日期 | 1996 |
卷号 | 105期号:3页码:193-201 |
关键词 | DIHYDRONICOTINAMIDE ADENINE-DINUCLEOTIDE CHEMICALLY MODIFIED ELECTRODES CARBON PASTE ELECTRODES ELECTROCHEMICAL OXIDATION CATALYTIC-OXIDATION NADH OXIDATION MELDOLA BLUE ADSORPTION GLUCOSE DEHYDROGENASE |
ISSN号 | 1381-1169 |
中文摘要 | twelve mediators have been modified by adsorption onto the paraffin impregnated graphite electrodes (ige). the resulting electrodes exhibit electrocatalytic activity of different degrees towards oxidation of 1,4-dihydronicotinamide adenine dinucleotide (nadh). the electrocatalytic ability of the chemically modified electrode (cme) depends mainly on the formal potential and molecular structure of mediator. the formation of the charge transfer complex between nadh and adsorbed mediator has been demonstrated by the experiments using a rotating disk electrode. an electrocatalytic scheme obeying michaelis-menten kinetics has been confirmed, and some kinetic parameters were estimated. the solution ph influences markedly the electrocatalytic activity of the modified electrode. various possible reasons are discussed. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-22 ; 2011-06-09 |
源URL | [http://ir.ciac.jl.cn/handle/322003/25557] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Chi QJ,Dong SJ. A comparison of electrocatalytic ability of various mediators adsorbed onto paraffin impregnated graphite electrodes for oxidation of reduced nicotinamide coenzymes[J]. journal of molecular catalysis a-chemical,1996,105(3):193-201. |
APA | Chi QJ,&Dong SJ.(1996).A comparison of electrocatalytic ability of various mediators adsorbed onto paraffin impregnated graphite electrodes for oxidation of reduced nicotinamide coenzymes.journal of molecular catalysis a-chemical,105(3),193-201. |
MLA | Chi QJ,et al."A comparison of electrocatalytic ability of various mediators adsorbed onto paraffin impregnated graphite electrodes for oxidation of reduced nicotinamide coenzymes".journal of molecular catalysis a-chemical 105.3(1996):193-201. |
入库方式: OAI收割
来源:长春应用化学研究所
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