中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
A comparison of electrocatalytic ability of various mediators adsorbed onto paraffin impregnated graphite electrodes for oxidation of reduced nicotinamide coenzymes

文献类型:期刊论文

作者Chi QJ ; Dong SJ
刊名journal of molecular catalysis a-chemical
出版日期1996
卷号105期号:3页码:193-201
关键词DIHYDRONICOTINAMIDE ADENINE-DINUCLEOTIDE CHEMICALLY MODIFIED ELECTRODES CARBON PASTE ELECTRODES ELECTROCHEMICAL OXIDATION CATALYTIC-OXIDATION NADH OXIDATION MELDOLA BLUE ADSORPTION GLUCOSE DEHYDROGENASE
ISSN号1381-1169
中文摘要twelve mediators have been modified by adsorption onto the paraffin impregnated graphite electrodes (ige). the resulting electrodes exhibit electrocatalytic activity of different degrees towards oxidation of 1,4-dihydronicotinamide adenine dinucleotide (nadh). the electrocatalytic ability of the chemically modified electrode (cme) depends mainly on the formal potential and molecular structure of mediator. the formation of the charge transfer complex between nadh and adsorbed mediator has been demonstrated by the experiments using a rotating disk electrode. an electrocatalytic scheme obeying michaelis-menten kinetics has been confirmed, and some kinetic parameters were estimated. the solution ph influences markedly the electrocatalytic activity of the modified electrode. various possible reasons are discussed.
收录类别SCI收录期刊论文
语种英语
公开日期2010-12-22 ; 2011-06-09
源URL[http://ir.ciac.jl.cn/handle/322003/25557]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
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Chi QJ,Dong SJ. A comparison of electrocatalytic ability of various mediators adsorbed onto paraffin impregnated graphite electrodes for oxidation of reduced nicotinamide coenzymes[J]. journal of molecular catalysis a-chemical,1996,105(3):193-201.
APA Chi QJ,&Dong SJ.(1996).A comparison of electrocatalytic ability of various mediators adsorbed onto paraffin impregnated graphite electrodes for oxidation of reduced nicotinamide coenzymes.journal of molecular catalysis a-chemical,105(3),193-201.
MLA Chi QJ,et al."A comparison of electrocatalytic ability of various mediators adsorbed onto paraffin impregnated graphite electrodes for oxidation of reduced nicotinamide coenzymes".journal of molecular catalysis a-chemical 105.3(1996):193-201.

入库方式: OAI收割

来源:长春应用化学研究所

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