Studies on organolanthanide complexes .58. Syntheses of 1,1'-(3-oxa-pentamethylene)dicyclopentadienyl divalent organolanthanides (Ln=Sm, Yb) and X-ray molecular structure of O(CH2CH2C5H4)(2)Yb(DME)
文献类型:期刊论文
作者 | Qian CT ; Zhu CJ ; Lin YH ; Xing Y |
刊名 | journal of organometallic chemistry
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出版日期 | 1996 |
卷号 | 507期号:1-2页码:41-45 |
关键词 | CRYSTAL-STRUCTURE REACTIVITY METAL (C5ME5)2SM(THF)2 |
ISSN号 | 0022-328x |
通讯作者 | qian ct |
中文摘要 | the compounds o(ch2ch2c5h4)(2)ln(thf)(2) [ln = sm(1), yb(2)] were synthesized by the reduction of o(ch2ch2c5h4)(2)lncl with sodium metal in tetrahydrofuran (thf) at room temperature. recrystallization of 2 from dimethoxyethane (dme) produced the single-crystal o(ch2ch2c5h4)(2)yb(dme) (3) whose structure has been determined by an x-ray diffraction study. the crystals are orthorhombic, space group pcab, with a = 14.168(4), b = 13.541(6), c = 19.314(8) angstrom, z = 8, d-calc. = 1.66 g cm(-3). |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-22 ; 2011-06-09 |
源URL | [http://ir.ciac.jl.cn/handle/322003/25617] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Qian CT,Zhu CJ,Lin YH,et al. Studies on organolanthanide complexes .58. Syntheses of 1,1'-(3-oxa-pentamethylene)dicyclopentadienyl divalent organolanthanides (Ln=Sm, Yb) and X-ray molecular structure of O(CH2CH2C5H4)(2)Yb(DME)[J]. journal of organometallic chemistry,1996,507(1-2):41-45. |
APA | Qian CT,Zhu CJ,Lin YH,&Xing Y.(1996).Studies on organolanthanide complexes .58. Syntheses of 1,1'-(3-oxa-pentamethylene)dicyclopentadienyl divalent organolanthanides (Ln=Sm, Yb) and X-ray molecular structure of O(CH2CH2C5H4)(2)Yb(DME).journal of organometallic chemistry,507(1-2),41-45. |
MLA | Qian CT,et al."Studies on organolanthanide complexes .58. Syntheses of 1,1'-(3-oxa-pentamethylene)dicyclopentadienyl divalent organolanthanides (Ln=Sm, Yb) and X-ray molecular structure of O(CH2CH2C5H4)(2)Yb(DME)".journal of organometallic chemistry 507.1-2(1996):41-45. |
入库方式: OAI收割
来源:长春应用化学研究所
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