Ac voltammetric and square wave voltammetric study of the self-assembled monolayers of thiol-functionalized viologen derivative
文献类型：期刊论文
| 作者 | Li JH ; Yang CH ; Yan JC ; Chen WQ ; Dong SJ |
| 刊名 | chinese journal of chemistry
 |
| 出版日期 | 1997 |
| 卷号 | 15期号:2页码:130-137 |
| 关键词 | ELECTRON-TRANSFER GOLD ELECTRODES SURFACES IMPEDANCE |
| ISSN号 | 1001-604x |
| 中文摘要 | electroactive self-assembled monolayers (sams) containing viologen group are formed through the adsorption of thiol-functionalized viologen compound ch3(ch2)(9)v2+(ch2)(8)sh, where v2+ is n,n'-dialkylbipyridinium (i.e. a viologen group), onto gold electrodes from methanol/water solution and its electrochemical behavior is investigated ty ac voltammetry and square wave voltammetry, which have the high sensitivity against background charging. the viologen sam formed is a sub-monolayer and the normal potentials corresponding to the two successive one-electron transfer processes of the active centers (viologen) are -360 mv and -750 mv (vs. ag/agcl) in 0.1 mol/l phosphate buffer solutions (ph 6.96) respectively, and the standard electron transfer rate constant is 9.0 s(-1). the electrochemical behavior of this sam in various solutions has been preliminarily discussed. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-28 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/26321]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Li JH,Yang CH,Yan JC,et al. Ac voltammetric and square wave voltammetric study of the self-assembled monolayers of thiol-functionalized viologen derivative[J]. chinese journal of chemistry,1997,15(2):130-137. |
| APA | Li JH,Yang CH,Yan JC,Chen WQ,&Dong SJ.(1997).Ac voltammetric and square wave voltammetric study of the self-assembled monolayers of thiol-functionalized viologen derivative.chinese journal of chemistry,15(2),130-137. |
| MLA | Li JH,et al."Ac voltammetric and square wave voltammetric study of the self-assembled monolayers of thiol-functionalized viologen derivative".chinese journal of chemistry 15.2(1997):130-137. |
入库方式： OAI收割
来源：长春应用化学研究所
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