Preparation and crystal structures of LaCl3(15-crown-5) and [LaCl2(phen)(H2O)(2)(mu-Cl)](2)center dot(15-crown-5)center dot MeCN
文献类型：期刊论文
| 作者 | Mao JG ; Jin ZS ; Ni JZ |
| 刊名 | journal of coordination chemistry
 |
| 出版日期 | 1995 |
| 卷号 | 34期号:3页码:195-202 |
| 关键词 | CROWN ETHER COMPLEXES GLYCOL COMPLEXES CRYSTALLIZATION 15-CROWN-5 |
| ISSN号 | 0095-8972 |
| 中文摘要 | lacl3(15-crown-5), i was prepared by the reaction of lacl(3)nh(2)o with 15-crown-5 and bipy (2,2'-bipyridyl). [lacl2(phen)(h2o)(2)(mu-cl)](2) .(15-crown-5). mecn, ii, was crystallized from a mixture of lac1(3) . nh(2)o, phen (1,10-phenanthroline) and 15-crown-5 in meoh/mecn, crystal structures of these two complexes have been determined by x-ray methods. the la(iii) ion in i is coordinated by three cl anions and five oxygen atoms of a crown ether. the two metal ions in ii are bridged by two cl anions and the crown ligand is hydrogen-bonded to the coordinated water molecules to form polymeric... crown/cation/cation/crown... chains. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-30 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/26339]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Mao JG,Jin ZS,Ni JZ. Preparation and crystal structures of LaCl3(15-crown-5) and [LaCl2(phen)(H2O)(2)(mu-Cl)](2)center dot(15-crown-5)center dot MeCN[J]. journal of coordination chemistry,1995,34(3):195-202. |
| APA | Mao JG,Jin ZS,&Ni JZ.(1995).Preparation and crystal structures of LaCl3(15-crown-5) and [LaCl2(phen)(H2O)(2)(mu-Cl)](2)center dot(15-crown-5)center dot MeCN.journal of coordination chemistry,34(3),195-202. |
| MLA | Mao JG,et al."Preparation and crystal structures of LaCl3(15-crown-5) and [LaCl2(phen)(H2O)(2)(mu-Cl)](2)center dot(15-crown-5)center dot MeCN".journal of coordination chemistry 34.3(1995):195-202. |
入库方式： OAI收割
来源：长春应用化学研究所
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