POLY(AZOMETHINE SULFONES) WITH THERMOTROPIC LIQUID-CRYSTALLINE BEHAVIOR
文献类型:期刊论文
作者 | COZAN V ; BUTUC E ; STOLERU A ; RUSA M ; RUSU M ; NI YS ; DING MX |
刊名 | journal of macromolecular science-pure and applied chemistry
![]() |
出版日期 | 1995 |
卷号 | a32期号:7页码:1243-1262 |
关键词 | POLYMERS TRANSITIONS POLYCARBONATE |
ISSN号 | 1060-1325 |
通讯作者 | cozan v |
中文摘要 | new poly(azomethine sulfones) with linear structures containing sulfonyl bis(4-phenoxyphenylene) and oxo bis(benzylideneaniline) or methylene bis(benzylideneaniline) units were prepared in the conventional literature manner by condensing the dialdehyde sulfone monomer (v) with diamines such as 4,4'-oxydianiline (iiia) and 4,4'-methylenedianiline (iiib), or by condensing an azomethine biphenol (ix) with 4,4'-sulfonyldichlorobenzene (ii). three model compounds which reproduced the above structures were also synthesized. the resulting polymers were confirmed by ir, h-1-nmp, and elemental analysis, and were characterized by inherent viscosities, thermogravimetric analysis (tga), and x-ray diffraction. the thermotropic liquid crystalline (tlc) behavior was studied using polarization light microscopy (plm), thermooptical analysis (toa), and dsc. a nematic texture was observed only for 4,4'-oxydianiline-units-based polymers. the reaction of polymer viiib containing -ch2- links between the mesogens with the model compound ix led to polymer x which exhibited tlc behavior. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-30 ; 2011-06-10 |
源URL | [http://ir.ciac.jl.cn/handle/322003/26559] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | COZAN V,BUTUC E,STOLERU A,et al. POLY(AZOMETHINE SULFONES) WITH THERMOTROPIC LIQUID-CRYSTALLINE BEHAVIOR[J]. journal of macromolecular science-pure and applied chemistry,1995,a32(7):1243-1262. |
APA | COZAN V.,BUTUC E.,STOLERU A.,RUSA M.,RUSU M.,...&DING MX.(1995).POLY(AZOMETHINE SULFONES) WITH THERMOTROPIC LIQUID-CRYSTALLINE BEHAVIOR.journal of macromolecular science-pure and applied chemistry,a32(7),1243-1262. |
MLA | COZAN V,et al."POLY(AZOMETHINE SULFONES) WITH THERMOTROPIC LIQUID-CRYSTALLINE BEHAVIOR".journal of macromolecular science-pure and applied chemistry a32.7(1995):1243-1262. |
入库方式: OAI收割
来源:长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。