中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
POLY(AZOMETHINE SULFONES) WITH THERMOTROPIC LIQUID-CRYSTALLINE BEHAVIOR

文献类型:期刊论文

作者COZAN V ; BUTUC E ; STOLERU A ; RUSA M ; RUSU M ; NI YS ; DING MX
刊名journal of macromolecular science-pure and applied chemistry
出版日期1995
卷号a32期号:7页码:1243-1262
关键词POLYMERS TRANSITIONS POLYCARBONATE
ISSN号1060-1325
通讯作者cozan v
中文摘要new poly(azomethine sulfones) with linear structures containing sulfonyl bis(4-phenoxyphenylene) and oxo bis(benzylideneaniline) or methylene bis(benzylideneaniline) units were prepared in the conventional literature manner by condensing the dialdehyde sulfone monomer (v) with diamines such as 4,4'-oxydianiline (iiia) and 4,4'-methylenedianiline (iiib), or by condensing an azomethine biphenol (ix) with 4,4'-sulfonyldichlorobenzene (ii). three model compounds which reproduced the above structures were also synthesized. the resulting polymers were confirmed by ir, h-1-nmp, and elemental analysis, and were characterized by inherent viscosities, thermogravimetric analysis (tga), and x-ray diffraction. the thermotropic liquid crystalline (tlc) behavior was studied using polarization light microscopy (plm), thermooptical analysis (toa), and dsc. a nematic texture was observed only for 4,4'-oxydianiline-units-based polymers. the reaction of polymer viiib containing -ch2- links between the mesogens with the model compound ix led to polymer x which exhibited tlc behavior.
收录类别SCI收录期刊论文
语种英语
公开日期2010-12-30 ; 2011-06-10
源URL[http://ir.ciac.jl.cn/handle/322003/26559]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
COZAN V,BUTUC E,STOLERU A,et al. POLY(AZOMETHINE SULFONES) WITH THERMOTROPIC LIQUID-CRYSTALLINE BEHAVIOR[J]. journal of macromolecular science-pure and applied chemistry,1995,a32(7):1243-1262.
APA COZAN V.,BUTUC E.,STOLERU A.,RUSA M.,RUSU M.,...&DING MX.(1995).POLY(AZOMETHINE SULFONES) WITH THERMOTROPIC LIQUID-CRYSTALLINE BEHAVIOR.journal of macromolecular science-pure and applied chemistry,a32(7),1243-1262.
MLA COZAN V,et al."POLY(AZOMETHINE SULFONES) WITH THERMOTROPIC LIQUID-CRYSTALLINE BEHAVIOR".journal of macromolecular science-pure and applied chemistry a32.7(1995):1243-1262.

入库方式: OAI收割

来源:长春应用化学研究所

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