ELECTROCHEMICAL-BEHAVIOR OF BIS(2 /17-ARSENOTUNGSTATE) LANTHANATES AND THEIR ELECTROCATALYTIC REDUCTION FOR NITRITE
文献类型：期刊论文
| 作者 | XI XD ; WANG G ; LIU BF ; DONG SJ |
| 刊名 | electrochimica acta
 |
| 出版日期 | 1995 |
| 卷号 | 40期号:8页码:1025-1029 |
| 关键词 | IRON PORPHYRIN NITROUS-OXIDE AMMONIA FILM HETEROPOLY ELECTRODE ISOPOLY WATER |
| ISSN号 | 0013-4686 |
| 中文摘要 | a series of new catalysts, k-14[ln(as2w17o61)(2)]. xh(2)o (ln = la, pr, sm, eu, gd, tb, dy, tm and yb) which can electrocatalyze reduction of nitrite are presented and their electrochemical behavior is described in this paper. bis(2:17-arsenotungstate) lanthanates which are monovacant dawson derivatives, exhibit two 2-electron and one 1-electron waves, attributed to electron addition and removal from the tungsten-oxide framework that comprises each anion structure. the formal potentials of redox couples are dependent on solution ph. double-hump principle of formal potentials takes effect with increasing atomic number of lanthanide elements following their special electronic shell structure. the third waves of all the heteropolyanions have good electrocatalytic activities for nitrite reduction at ph 5.0. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-30 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/26619]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | XI XD,WANG G,LIU BF,et al. ELECTROCHEMICAL-BEHAVIOR OF BIS(2 /17-ARSENOTUNGSTATE) LANTHANATES AND THEIR ELECTROCATALYTIC REDUCTION FOR NITRITE[J]. electrochimica acta,1995,40(8):1025-1029. |
| APA | XI XD,WANG G,LIU BF,&DONG SJ.(1995).ELECTROCHEMICAL-BEHAVIOR OF BIS(2 /17-ARSENOTUNGSTATE) LANTHANATES AND THEIR ELECTROCATALYTIC REDUCTION FOR NITRITE.electrochimica acta,40(8),1025-1029. |
| MLA | XI XD,et al."ELECTROCHEMICAL-BEHAVIOR OF BIS(2 /17-ARSENOTUNGSTATE) LANTHANATES AND THEIR ELECTROCATALYTIC REDUCTION FOR NITRITE".electrochimica acta 40.8(1995):1025-1029. |
入库方式： OAI收割
来源：长春应用化学研究所
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