NMR-STUDY ON THE RELATIONSHIP BETWEEN MISCIBILITY AND ANTIAGING PERFORMANCE OF BLENDS CONTAINING BLOCK-COPOLYMERS
文献类型:期刊论文
作者 | FENG HQ ; YE CH ; FENG ZL |
刊名 | polymer journal
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出版日期 | 1995 |
卷号 | 27期号:4页码:420-428 |
关键词 | HOMOPOLYMER MIXTURES BINARY-MIXTURES BUTADIENE |
ISSN号 | 0032-3896 |
通讯作者 | feng hq |
中文摘要 | the anti-aging performance of blends of polystyrene (ps), styrene-butadiene triblock copolymers (sbs), and ps/styrene-butadiene (sb)-4a (carm star se block copolymer) has been studied by means of c-13 nmr techniques. it is found that the anti-aging performance of these kinds of blends largely depends on their miscibility with ps of different molecular weight m(ps). the larger the quantities of ps solubilized in polybutadiene (pbd) domains, the better the anti-aging performance of the blends. it is also found that the anti-aging performance of these blends has dependence on molecular architectures of the se block copolymers. for the aged blends, the double bonds of pbd were broken, meanwhile serious cross-linking networks formed in the blends. the proposed anti-aging mechanism is that the ps solubilized in pbd domains can efficiently prevent oxygen molecules from diffusing into pbd domains, therefore, successfully stop the oxidative process of pbd. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-30 ; 2011-06-10 |
源URL | [http://ir.ciac.jl.cn/handle/322003/26633] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | FENG HQ,YE CH,FENG ZL. NMR-STUDY ON THE RELATIONSHIP BETWEEN MISCIBILITY AND ANTIAGING PERFORMANCE OF BLENDS CONTAINING BLOCK-COPOLYMERS[J]. polymer journal,1995,27(4):420-428. |
APA | FENG HQ,YE CH,&FENG ZL.(1995).NMR-STUDY ON THE RELATIONSHIP BETWEEN MISCIBILITY AND ANTIAGING PERFORMANCE OF BLENDS CONTAINING BLOCK-COPOLYMERS.polymer journal,27(4),420-428. |
MLA | FENG HQ,et al."NMR-STUDY ON THE RELATIONSHIP BETWEEN MISCIBILITY AND ANTIAGING PERFORMANCE OF BLENDS CONTAINING BLOCK-COPOLYMERS".polymer journal 27.4(1995):420-428. |
入库方式: OAI收割
来源:长春应用化学研究所
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