STUDY OF THE ELECTROCATALYTIC REDUCTION OF NITRITE WITH SILICOTUNGSTIC HETEROPOLYANION
文献类型:期刊论文
作者 | DONG SJ ; XI XD ; TIAN M |
刊名 | journal of electroanalytical chemistry
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出版日期 | 1995 |
卷号 | 385期号:2页码:227-233 |
关键词 | HOMOGENEOUS CATALYTIC REACTIONS SOLUBLE IRON PORPHYRIN ELECTRODE-REACTIONS NITROUS-OXIDE AMMONIA WATER ULTRAMICROELECTRODES ELECTROCHEMISTRY MICROELECTRODES QUASI-1ST |
ISSN号 | 0022-0728 |
通讯作者 | dong sj |
中文摘要 | three couples of reversible redox waves of the siw12o404- anion which are composed of two one-electron and one two-electron processes occur in the potential range +0.1 to -0.7 v in aqueous solutions. the first (most positive) and third (most negative) redox waves exhibit good electrocatalytic activities for nitrite reduction in acid solutions with ph < 2 for the former and with ph similar or equal to 4 for the latter. the behavior of the third catalytic wave, which is quite unusual, was studied in detail. the rate constant governing the reduction of no2- by the first wave of siw12o404- was measured by an ultramicrodisk electrode as 3.73 x 10(3) m(-1) s(-1). |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2010-12-30 ; 2011-06-10 |
源URL | [http://ir.ciac.jl.cn/handle/322003/26639] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | DONG SJ,XI XD,TIAN M. STUDY OF THE ELECTROCATALYTIC REDUCTION OF NITRITE WITH SILICOTUNGSTIC HETEROPOLYANION[J]. journal of electroanalytical chemistry,1995,385(2):227-233. |
APA | DONG SJ,XI XD,&TIAN M.(1995).STUDY OF THE ELECTROCATALYTIC REDUCTION OF NITRITE WITH SILICOTUNGSTIC HETEROPOLYANION.journal of electroanalytical chemistry,385(2),227-233. |
MLA | DONG SJ,et al."STUDY OF THE ELECTROCATALYTIC REDUCTION OF NITRITE WITH SILICOTUNGSTIC HETEROPOLYANION".journal of electroanalytical chemistry 385.2(1995):227-233. |
入库方式: OAI收割
来源:长春应用化学研究所
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