SYNTHESES AND CRYSTAL-STRUCTURES OF (C8H8)ND(C5H9C5H4)(THF)(2) AND [(C8H8)GD(C5H9C4H4(THF)][(C8H8)GD(C5H9C5H4(THF)(2)]
文献类型：期刊论文
| 作者 | JIN JH ; ZHUANG XL ; JIN ZS ; CHEN WQ |
| 刊名 | journal of organometallic chemistry
 |
| 出版日期 | 1995 |
| 卷号 | 490期号:1-2页码:c8-c13 |
| 关键词 | LANTHANIDES |
| ISSN号 | 0022-328x |
| 中文摘要 | lncl(3) (ln = nd, gd) reacts with c5h9c5h4na (or k2c8h8) in thf (c5h9c5h4 = cyclopentylcyclopentadienyl) in the ratio of 1:1 to give (c5h9c5h4)lncl(2)(thf)(n) (or (c8h8)lncl(2)(thf)(n)], which further reacts with k2c8h8 (or c5h9c5h4na) in thf to form the title complexes. if ln = nd the complex (c8h8)nd(c5h9c5h4)(thf)(2) (a) was obtained: when ln = gd the 1:1 complex [(c8h8)gd(c5h9c5h4)(thf)][(c5h8)gd(c5h9c5h4)(thf)(2)] (b) was obtained in crystalline form. the crystal structure analysis shows that in (c8h8)ln(c5h9c5h4)(thf)(2) (ln = nd or gd), the cyclopentylcyclopentadienyl (eta(5)), cyclooctatetraenyl (eta(8)) and two oxygen atoms from thf are coordinated to nd3+ (or gd3+) with coordination number 10. the centroid of the cyclopentadienyl ring (cp') in c5h9c5h4 group, cyclooctatetraenyl centroid (cot) and two oxygens (thf) form a twisted tetrahedron around nd3+ (or gd3+). in (c8h8)gd(c5h9c5h4)(thf), the cyclopentyl-cyclopentadienyl (eta(5)), cyclooctatetraenyl (eta(8)) and one oxygen atom are coordinated to gd3+ with the coordination number of 9 and cp', cot and oxygen atom form a triangular plane around gd3+, which is almost in the plane (dev. - 0.0144 angstrom). |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-30 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/26677]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | JIN JH,ZHUANG XL,JIN ZS,et al. SYNTHESES AND CRYSTAL-STRUCTURES OF (C8H8)ND(C5H9C5H4)(THF)(2) AND [(C8H8)GD(C5H9C4H4(THF)][(C8H8)GD(C5H9C5H4(THF)(2)][J]. journal of organometallic chemistry,1995,490(1-2):c8-c13. |
| APA | JIN JH,ZHUANG XL,JIN ZS,&CHEN WQ.(1995).SYNTHESES AND CRYSTAL-STRUCTURES OF (C8H8)ND(C5H9C5H4)(THF)(2) AND [(C8H8)GD(C5H9C4H4(THF)][(C8H8)GD(C5H9C5H4(THF)(2)].journal of organometallic chemistry,490(1-2),c8-c13. |
| MLA | JIN JH,et al."SYNTHESES AND CRYSTAL-STRUCTURES OF (C8H8)ND(C5H9C5H4)(THF)(2) AND [(C8H8)GD(C5H9C4H4(THF)][(C8H8)GD(C5H9C5H4(THF)(2)]".journal of organometallic chemistry 490.1-2(1995):c8-c13. |
入库方式： OAI收割
来源：长春应用化学研究所
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