GAS-PHASE ACETYLATION OF C-60 AND C-70 BY ION/MOLECULE REACTIONS
文献类型：期刊论文
| 作者 | LIU ZY ; HAO GL ; GUO XH ; LIU SY |
| 刊名 | rapid communications in mass spectrometry
 |
| 出版日期 | 1995 |
| 卷号 | 9期号:3页码:213-214 |
| 关键词 | ISOMERIC |
| ISSN号 | 0951-4198 |
| 中文摘要 | gas phase reactions of c-60 and c-70 with the ion system of acetone under chemical ionization conditions have been studied. c-60 and c-70 can react with acetyl and oxonium ions, which come from self-chemical ionization of acetone, to form adduct ions. in addition, c-60 and c-70 can accept protons to produce protonated ions. c-70 is more active in the above reactions than c-60 because of its stronger gas-phase basicity. a sigma-bond between c-60 and an acyl carbon atom can be formed to produce stable acetylated c-60 ions. the above results may be relevant to the acetylation reactions of c-60 in the condensed phase. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-30 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/26717]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | LIU ZY,HAO GL,GUO XH,et al. GAS-PHASE ACETYLATION OF C-60 AND C-70 BY ION/MOLECULE REACTIONS[J]. rapid communications in mass spectrometry,1995,9(3):213-214. |
| APA | LIU ZY,HAO GL,GUO XH,&LIU SY.(1995).GAS-PHASE ACETYLATION OF C-60 AND C-70 BY ION/MOLECULE REACTIONS.rapid communications in mass spectrometry,9(3),213-214. |
| MLA | LIU ZY,et al."GAS-PHASE ACETYLATION OF C-60 AND C-70 BY ION/MOLECULE REACTIONS".rapid communications in mass spectrometry 9.3(1995):213-214. |
入库方式： OAI收割
来源：长春应用化学研究所
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