MOSSBAUER-EFFECT STUDIES OF A NEW ORGANOEUROPIUM COMPLEX [EU(ETA-6-C6ME6)(ALCL4)2]4
文献类型：期刊论文
| 作者 | JIA YQ ; LIANG HZ ; SHEN Q ; JIN MZ ; LIU ML ; LIU XW |
| 刊名 | physica status solidi a-applied research
 |
| 出版日期 | 1995 |
| 卷号 | 147期号:1页码:249-255 |
| ISSN号 | 0031-8965 |
| 关键词 | NEUTRAL PI-LIGAND TETRACHLORIDES) MOLECULES EU-151 |
| 通讯作者 | jia yq |
| 中文摘要 | the mossbauer spectrum of a new organoeuropium complex with a neutral pi-ligand, eu(eta6-c6me6) (alcl4)2, is measured at 88 k. the mossbauer parameters derived from the spectrum show the divalent nature of the europium ion in this organoeuropium complex. the calculations of the electric field gradient at the eu nucleus in the crystal indicate that the eu-cl bond in the compound may possess a certain covalent character. the low debye temperature of this complex may be attributed to weak and delocalized pi-bonding between the eu atom and the benzene ring of hexamethylbenzene, and a slow paramagnetic relaxation is suggested by the mossbauer effect. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2010-12-30 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/26719]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | JIA YQ,LIANG HZ,SHEN Q,et al. MOSSBAUER-EFFECT STUDIES OF A NEW ORGANOEUROPIUM COMPLEX [EU(ETA-6-C6ME6)(ALCL4)2]4[J]. physica status solidi a-applied research,1995,147(1):249-255. |
| APA | JIA YQ,LIANG HZ,SHEN Q,JIN MZ,LIU ML,&LIU XW.(1995).MOSSBAUER-EFFECT STUDIES OF A NEW ORGANOEUROPIUM COMPLEX [EU(ETA-6-C6ME6)(ALCL4)2]4.physica status solidi a-applied research,147(1),249-255. |
| MLA | JIA YQ,et al."MOSSBAUER-EFFECT STUDIES OF A NEW ORGANOEUROPIUM COMPLEX [EU(ETA-6-C6ME6)(ALCL4)2]4".physica status solidi a-applied research 147.1(1995):249-255. |
入库方式： OAI收割
来源：长春应用化学研究所
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