SYNTHESIS AND PROPELLER-PROPELLER TRANSITION OF OPTICALLY-ACTIVE POLY(DIPHENYL-O-TOLYLMETHYL METHACRYLATE)
文献类型：期刊论文
| 作者 | YU B ; DING MX ; WANG YC ; WANG FS |
| 刊名 | journal of polymer science part a-polymer chemistry
 |
| 出版日期 | 1993 |
| 卷号 | 31期号:11页码:2681-2685 |
| 关键词 | POLY(TRIPHENYLMETHYL METHACRYLATE) |
| ISSN号 | 0887-624x |
| 通讯作者 | yu b |
| 中文摘要 | diphenyl-o-tolylmethyl methacrylate (dptma) was synthesized and polymerized using initiators of organolithium complexes with (+) - (2s,3s) -dimethoxy-1,4-bis(dimethylamino) butane (ddb) and (-) -sparteine (sp) as the chiral ligands. ddb was suitable for its complex effective to prepare optically active poly(diphenyl-o-tolylmethyl methacrylate) (pdptma) with one-handed helical conformation, whereas only low-molecular weight polymer was formed when sp was used as ligand due to the repulsive hindrance between the triarylmethyl group and the ligand. a new mutarotation, propeller-propeller transition, was observed for pdptma from the optical rotation curves and cd spectra in thf solution. the equivalent period of pdptma was estimated to be 14 angstrom based on the x-ray diffraction. (c) 1993 john wiley & sons, inc. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2011-01-19 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/36053]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | YU B,DING MX,WANG YC,et al. SYNTHESIS AND PROPELLER-PROPELLER TRANSITION OF OPTICALLY-ACTIVE POLY(DIPHENYL-O-TOLYLMETHYL METHACRYLATE)[J]. journal of polymer science part a-polymer chemistry,1993,31(11):2681-2685. |
| APA | YU B,DING MX,WANG YC,&WANG FS.(1993).SYNTHESIS AND PROPELLER-PROPELLER TRANSITION OF OPTICALLY-ACTIVE POLY(DIPHENYL-O-TOLYLMETHYL METHACRYLATE).journal of polymer science part a-polymer chemistry,31(11),2681-2685. |
| MLA | YU B,et al."SYNTHESIS AND PROPELLER-PROPELLER TRANSITION OF OPTICALLY-ACTIVE POLY(DIPHENYL-O-TOLYLMETHYL METHACRYLATE)".journal of polymer science part a-polymer chemistry 31.11(1993):2681-2685. |
入库方式： OAI收割
来源：长春应用化学研究所
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