SYNTHESIS AND PROPELLER PROPELLER TRANSITION OF OPTICALLY-ACTIVE POLY(DIPHENYL-O-METHOXYPHENYLMETHYL METHACRYLATE)
文献类型：期刊论文
| 作者 | YU B ; DING MX ; WANG FS |
| 刊名 | polymer
 |
| 出版日期 | 1993 |
| 卷号 | 34期号:15页码:3340-3342 |
| 关键词 | POLY(TRIPHENYLMETHYL METHACRYLATE) |
| ISSN号 | 0032-3861 |
| 中文摘要 | diphenyl-o-methoxyphenylmethyl methacrylate was polymerized with several organolithium complexes of chiral ligand such as (-)-sparteine (sp) and (s,s)-(+)-2,3-dimethoxy-1,4-bis(dimethylamino)butane (ddb). (+)-ddb was effective in preparing a polymer of high optical rotation, whereas (-)-sp only gave oligomers with low optical rotation for the repulsive hindrance between the bulky ester group and the rigid ligand. the optical rotation of the polymer decreased rapidly to a constant value due to the propeller-propeller transition, which has been demonstrated by h-1 n.m.r. and circular dichroic spectra. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2011-01-19 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/36069]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | YU B,DING MX,WANG FS. SYNTHESIS AND PROPELLER PROPELLER TRANSITION OF OPTICALLY-ACTIVE POLY(DIPHENYL-O-METHOXYPHENYLMETHYL METHACRYLATE)[J]. polymer,1993,34(15):3340-3342. |
| APA | YU B,DING MX,&WANG FS.(1993).SYNTHESIS AND PROPELLER PROPELLER TRANSITION OF OPTICALLY-ACTIVE POLY(DIPHENYL-O-METHOXYPHENYLMETHYL METHACRYLATE).polymer,34(15),3340-3342. |
| MLA | YU B,et al."SYNTHESIS AND PROPELLER PROPELLER TRANSITION OF OPTICALLY-ACTIVE POLY(DIPHENYL-O-METHOXYPHENYLMETHYL METHACRYLATE)".polymer 34.15(1993):3340-3342. |
入库方式： OAI收割
来源：长春应用化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。