APPLICATION OF AN ULTRAMICROELECTRODE IN HOMOGENEOUS CATALYTIC REACTIONS .4. ELECTROCATALYTIC REDUCTION OF ORGANOHALIDES BY METALLOPORPHYRIN AT ULTRAMICROELECTRODE
文献类型：期刊论文
| 作者 | CHE GL ; DONG SJ |
| 刊名 | electrochimica acta
 |
| 出版日期 | 1993 |
| 卷号 | 38期号:10页码:1345-1349 |
| 关键词 | CARBON BOND FORMATION ALKYL-HALIDES NUCLEOPHILIC-SUBSTITUTION ELECTROCHEMICAL REDUCTION VICINAL DIBROMIDES IRON PORPHYRINS VITAMIN-B12 ELECTRODES RADICALS |
| ISSN号 | 0013-4686 |
| 中文摘要 | the electrocatalytic reduction of 1,2-dibromoethane and tetrabromoethane with cotpp in dmf solutions containing 0.1 m tbap was investigated at a pt ultramicroelectrode. the experimental results indicated that cotpp obviously exhibited catalytic activity for 1,2-dibromoethane and tetrabromoethane. the rate constants of 1,2-dibromoethane and tetrabromoethane in this system were calculated to be 0.14 x 10(3) and 0.5 x 10(2) m-1 s-1, respectively. the reaction mechanism of 1,2-dibromoethane and tetrabromoethane reduction electrocatalysed by cotpp in 0.1 m tbap dmf solution is discussed. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| 公开日期 | 2011-01-19 ; 2011-06-10 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/36141]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | CHE GL,DONG SJ. APPLICATION OF AN ULTRAMICROELECTRODE IN HOMOGENEOUS CATALYTIC REACTIONS .4. ELECTROCATALYTIC REDUCTION OF ORGANOHALIDES BY METALLOPORPHYRIN AT ULTRAMICROELECTRODE[J]. electrochimica acta,1993,38(10):1345-1349. |
| APA | CHE GL,&DONG SJ.(1993).APPLICATION OF AN ULTRAMICROELECTRODE IN HOMOGENEOUS CATALYTIC REACTIONS .4. ELECTROCATALYTIC REDUCTION OF ORGANOHALIDES BY METALLOPORPHYRIN AT ULTRAMICROELECTRODE.electrochimica acta,38(10),1345-1349. |
| MLA | CHE GL,et al."APPLICATION OF AN ULTRAMICROELECTRODE IN HOMOGENEOUS CATALYTIC REACTIONS .4. ELECTROCATALYTIC REDUCTION OF ORGANOHALIDES BY METALLOPORPHYRIN AT ULTRAMICROELECTRODE".electrochimica acta 38.10(1993):1345-1349. |
入库方式： OAI收割
来源：长春应用化学研究所
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