MISCIBILITY AND PHASE-BEHAVIOR IN BLENDS OF POLY(HYDROXYETHER OF BISPHENOL-A) WITH POLY(ETHYLENE OXIDE-CO-PROPYLENE OXIDE)
文献类型:期刊论文
作者 | GUO QP ; SUN KS ; FANG TR ; QI YC ; FENG ZL |
刊名 | journal of applied polymer science
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出版日期 | 1993 |
卷号 | 48期号:3页码:547-556 |
关键词 | METHYL-METHACRYLATE COPOLYMERS POLYMER BLENDS POLY(2,6-DIMETHYL-1,4-PHENYLENE OXIDE) POLY(METHYL METHACRYLATE) STYRENE-ACRYLONITRILE A POLYCARBONATE POLY(STYRENE-CO-ACRYLONITRILE) COMPATIBILITY ACETATE) CRYSTALLIZATION |
ISSN号 | 0021-8995 |
中文摘要 | the miscibility of poly(hydroxyether of bisphenol a) (phenoxy) with a series of poly(ethylene oxide-co-propylene oxide) (epo) has been studied. it was found that the critical copolymer composition for achieving miscibility with phenoxy around 60-degrees-c is about 22 mol % ethylene oxide (eo). some blends undergo phase separation at elevated temperatures, but there is no maximum in the miscibility window. the mean-field approach has been used to describe this homopolymer/copolymer system. from the miscibility maps and the melting-point depression of the crystallizable component in the blends, the binary interaction energy densities, b(ij), have been calculated for all three pairs. the miscibility of phenoxy with epo is considered to be caused mainly by the intermolecular hydrogen-bonding interactions between the hydroxyl groups of phenoxy and the ether oxygens of the eo units in the copolymers, while the intramolecular repulsion between eo and propylene oxide units in the copolymers contributes relatively little to the miscibility. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
公开日期 | 2011-01-19 ; 2011-06-10 |
源URL | [http://ir.ciac.jl.cn/handle/322003/36241] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | GUO QP,SUN KS,FANG TR,et al. MISCIBILITY AND PHASE-BEHAVIOR IN BLENDS OF POLY(HYDROXYETHER OF BISPHENOL-A) WITH POLY(ETHYLENE OXIDE-CO-PROPYLENE OXIDE)[J]. journal of applied polymer science,1993,48(3):547-556. |
APA | GUO QP,SUN KS,FANG TR,QI YC,&FENG ZL.(1993).MISCIBILITY AND PHASE-BEHAVIOR IN BLENDS OF POLY(HYDROXYETHER OF BISPHENOL-A) WITH POLY(ETHYLENE OXIDE-CO-PROPYLENE OXIDE).journal of applied polymer science,48(3),547-556. |
MLA | GUO QP,et al."MISCIBILITY AND PHASE-BEHAVIOR IN BLENDS OF POLY(HYDROXYETHER OF BISPHENOL-A) WITH POLY(ETHYLENE OXIDE-CO-PROPYLENE OXIDE)".journal of applied polymer science 48.3(1993):547-556. |
入库方式: OAI收割
来源:长春应用化学研究所
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