中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
MISCIBILITY AND PHASE-BEHAVIOR IN BLENDS OF POLY(HYDROXYETHER OF BISPHENOL-A) WITH POLY(ETHYLENE OXIDE-CO-PROPYLENE OXIDE)

文献类型:期刊论文

作者GUO QP ; SUN KS ; FANG TR ; QI YC ; FENG ZL
刊名journal of applied polymer science
出版日期1993
卷号48期号:3页码:547-556
关键词METHYL-METHACRYLATE COPOLYMERS POLYMER BLENDS POLY(2,6-DIMETHYL-1,4-PHENYLENE OXIDE) POLY(METHYL METHACRYLATE) STYRENE-ACRYLONITRILE A POLYCARBONATE POLY(STYRENE-CO-ACRYLONITRILE) COMPATIBILITY ACETATE) CRYSTALLIZATION
ISSN号0021-8995
中文摘要the miscibility of poly(hydroxyether of bisphenol a) (phenoxy) with a series of poly(ethylene oxide-co-propylene oxide) (epo) has been studied. it was found that the critical copolymer composition for achieving miscibility with phenoxy around 60-degrees-c is about 22 mol % ethylene oxide (eo). some blends undergo phase separation at elevated temperatures, but there is no maximum in the miscibility window. the mean-field approach has been used to describe this homopolymer/copolymer system. from the miscibility maps and the melting-point depression of the crystallizable component in the blends, the binary interaction energy densities, b(ij), have been calculated for all three pairs. the miscibility of phenoxy with epo is considered to be caused mainly by the intermolecular hydrogen-bonding interactions between the hydroxyl groups of phenoxy and the ether oxygens of the eo units in the copolymers, while the intramolecular repulsion between eo and propylene oxide units in the copolymers contributes relatively little to the miscibility.
收录类别SCI收录期刊论文
语种英语
公开日期2011-01-19 ; 2011-06-10
源URL[http://ir.ciac.jl.cn/handle/322003/36241]  
专题长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式
GB/T 7714
GUO QP,SUN KS,FANG TR,et al. MISCIBILITY AND PHASE-BEHAVIOR IN BLENDS OF POLY(HYDROXYETHER OF BISPHENOL-A) WITH POLY(ETHYLENE OXIDE-CO-PROPYLENE OXIDE)[J]. journal of applied polymer science,1993,48(3):547-556.
APA GUO QP,SUN KS,FANG TR,QI YC,&FENG ZL.(1993).MISCIBILITY AND PHASE-BEHAVIOR IN BLENDS OF POLY(HYDROXYETHER OF BISPHENOL-A) WITH POLY(ETHYLENE OXIDE-CO-PROPYLENE OXIDE).journal of applied polymer science,48(3),547-556.
MLA GUO QP,et al."MISCIBILITY AND PHASE-BEHAVIOR IN BLENDS OF POLY(HYDROXYETHER OF BISPHENOL-A) WITH POLY(ETHYLENE OXIDE-CO-PROPYLENE OXIDE)".journal of applied polymer science 48.3(1993):547-556.

入库方式: OAI收割

来源:长春应用化学研究所

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